Journal of the American Chemical Society p. 2767 - 2772 (1990)
Update date:2022-08-05
Topics:
Oppolzer, Wolfgang
Blagg, Julian
Rodriguez, Inès
Walther, Eric
N-acylsultams 2 furnish, via aldolization of their enolates 16 with aldehydes, diastereomerically pure, crystalline syn aldols. The absolute configuration of the product is controlled by the choice of the enolate counterion: 16, M = B → 3; 16, M = Li or S
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