Green Chemistry p. 130 - 135 (2018)
Update date:2022-08-04
Topics:
Pang, Haobo
Gallou, Fabrice
Sohn, Hyuntae
Camacho-Bunquin, Jeffrey
Delferro, Massimiliano
Lipshutz, Bruce H.
A remarkable synergistic effect has been uncovered between ppm levels of Pd and Ni embedded within iron nanoparticles that leads to mild and selective catalytic reductions of nitro-containing aromatics and heteroaromatics in water at room temperature. NaBH4 serves as the source of inexpensive hydride. Broad substrate scope is documented, along with several other features including: low catalyst loading, low residual metal in the products, and recycling of the catalyst and reaction medium, highlight the green nature of this new technology.
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