1,9-DIAMINONONANE

Base Information

• Chemical Name: 1,9-DIAMINONONANE
• CAS No.: 646-24-2
• Molecular Formula: C9H22 N2
• Molecular Weight: 158.287
• Hs Code.: 2921290000
• European Community (EC) Number: 211-470-3
• DSSTox Substance ID: DTXSID20214849
• Nikkaji Number: J149.316G
• Wikidata: Q83090754
• ChEMBL ID: CHEMBL572025
• Mol file: 646-24-2.mol

Synonyms:1,9-Diaminononane;1,9-Nonamethylenediamine; Nonamethylenediamine

Chemical Property of 1,9-DIAMINONONANE

Chemical Property:

• Appearance/Colour: White to slightly yellow low melting solid
• Vapor Pressure: 0.0135mmHg at 25°C
• Melting Point: 35-37 °C(lit.)
• Refractive Index: 1.4686 (estimate)
• Boiling Point: 258-259 °C756 mm Hg(lit.)
• PKA: 10.97±0.10(Predicted)
• Flash Point: >230 °F
• PSA: 52.04000
• Density: 0.858 g/cm³
• LogP: 3.03510
• Storage Temp.: Keep in dark place,Inert atmosphere,Room temperature
• Sensitive.: Air Sensitive
• Water Solubility.: Soluble in water.
• XLogP3: 1.8
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 8
• Exact Mass: 158.178298710
• Heavy Atom Count: 11
• Complexity: 56.6

Purity/Quality:

99.9% ^*data from raw suppliers

1,9-Diaminononane ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C(CCCCN)CCCCN
• Uses: 1,9-Diaminononane is used as an organic intermediate. It is also used to detect spermine and spermidine by matrix-assisted laser desorption/ionization combined with time-of-flight mass spectrometry ( MALDI-TOF MS) in foods and for the identification of apoptosis-related proteins by nano-flow ultra-performance liquid chromatography tandem mass-spectrometry (UPLC-MS/MS) after treatment with spermine and spermidine.

Technology Process of 1,9-DIAMINONONANE

There total 9 articles about 1,9-DIAMINONONANE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

1,11-undecanediamide (73154-82-2) → 1.9-diaminononane (646-24-2)

Guidance literature:

With sodium hypochlorite; sodium hydroxide; In 1,4-dioxane; at 10 - 75 ℃; for 3h; pH=10 - 11; pH-value; Solvent;

Reference yield: 88.0%

nonanedinitrile (1675-69-0) → 1.9-diaminononane (646-24-2)

Guidance literature:

With ammonia; hydrogen; sodium hydroxide; Raney nickel; In water; at 130 ℃; for 6h; under 22502.3 Torr; Product distribution / selectivity; Autoclave;

Reference yield: 44.0%

2,2-(nonane-1,9-diyl)bis(isoindole-1,3-dione) (37830-04-9) → 1.9-diaminononane (646-24-2)

Guidance literature:

With hydrazine hydrate; In ethanol; Reflux;

upstream raw materials:

diethyl ether

nonanedinitrile

azelaic acid

1,9-Nonanediol

Downstream raw materials:

(1E,9E)-2,2'-[nonane-1,9-diylbis(nitrilomethylidyne)]diphenol

N,N'-Nonamethylendi-(chloracetamid)

C₂₅H₂₈F₆N₂O₄

C₂₅H₃₄N₂O₄

Refernces

• 1、 -. "Synthesis method of 1,9-diaminononane". Paragraph 0048; 0052; 0050; 0051; 0054; 0055. . Retrieved 2019/03/26.
• 2、 -. "Synthetic method of 1,9-diaminononane". . . Retrieved 2018/11/22.