Lithium (2H)hydroxide

Base Information

• Chemical Name: Lithium (2H)hydroxide
• CAS No.: 12159-20-5
• Molecular Formula: DLiO
• Molecular Weight: 24.9404
• European Community (EC) Number: 235-287-3
• DSSTox Substance ID: DTXSID301311607
• Mol file: 12159-20-5.mol

Synonyms:12159-20-5;Lithium (2H)hydroxide;EINECS 235-287-3;Lithium hydroxide (Li(OD)) (6CI,7CI,8CI,9CI);LiOD;Lithium hydroxide (Li(OD));WMFOQBRAJBCJND-DYCDLGHISA-M;DTXSID301311607;AKOS015903816;J-004543

Chemical Property of Lithium (2H)hydroxide

Chemical Property:

• Refractive Index: n20/D 1.363
• PSA: 23.06000
• LogP: -0.17680
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 25.02501983
• Heavy Atom Count: 2
• Complexity: 2

Purity/Quality:

99% ^*data from raw suppliers

LithiumDeuteroxide(d,99.5%)3nind2o ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: C,Xn
• Statements: 20/21/22-34-36/38-22
• Safety Statements: 26-27-28-36/37/39-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [Li+].[OH-]
• Isomeric SMILES: [2H][O-].[Li+]

Technology Process of Lithium (2H)hydroxide

There total 3 articles about Lithium (2H)hydroxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

water-d2 (7789-20-0) + lithium (7439-93-2) → LiOD (12159-20-5)

Guidance literature:

In water-d2;

DOI:10.1016/S0009-2614(00)01169-6

Reference yield:

lithium peroxide + water-d2 (7789-20-0) → LiOD (12159-20-5)

Guidance literature:

In water-d2; excess of D2O, heating (1 h, 90°C); solvent removal, storing in vac.;

Reference yield:

water (7732-18-5) + water-d2 (7789-20-0) + lithium (7439-93-2) → LiOD (12159-20-5) + lithium hydroxide (1310-65-2)

Guidance literature:

In water; dissolving Li in mixt. of H2O and (2)H2O under Ar atmosphere; H/(2)H ratio in electrolyte 0.22+/-0.01;

DOI:10.1016/j.jpcs.2007.08.005

upstream raw materials:

water

water-d2

lithium

Refernces

• 1、 Ma, Zhiru,Zheng, Jim P.,Fu, Riqiang. "Solid state NMR investigation of hydrous ruthenium oxide". . p. 64 - 70. Retrieved 2000.
• 2、 Nikitina,Nikitina,Rosolovskii. "Inhibition of Thermal Decomposition of Lithium Chlorate and Formation of the Compound LiOH · LiClO3 in the Lithium Chlorate-Lithium Hydroxide System". . p. 927 - 931. Retrieved 2008/10/08.