1-bromo-3,5-bis(octyloxy)phenyl

Base Information

• Chemical Name: 1-bromo-3,5-bis(octyloxy)phenyl
• CAS No.: 937390-20-0
• Molecular Formula: C₂₂H₃₇BrO₂
• Molecular Weight: 413.439
• Mol file: 937390-20-0.mol

Synonyms:1-bromo-3,5-bis(octyloxy)phenyl

Chemical Property of 1-bromo-3,5-bis(octyloxy)phenyl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-bromo-3,5-bis(octyloxy)phenyl

There total 7 articles about 1-bromo-3,5-bis(octyloxy)phenyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.8%

1-bromo-octane (111-83-1) + 5-bromoresorcinol (106120-04-1) → 1-bromo-3,5-bis(octyloxy)phenyl (937390-20-0)

Guidance literature:

5-bromoresorcinol; With potassium carbonate; In N,N-dimethyl-formamide; at 20 ℃; for 0.5h;

1-bromo-octane; In N,N-dimethyl-formamide; at 60 ℃;

DOI:10.1039/c4ra10154e

Reference yield:

1-bromo-3,5-dimethoxybenzene (20469-65-2) → 1-bromo-3,5-bis(octyloxy)phenyl (937390-20-0)

Guidance literature:

Multi-step reaction with 2 steps

1: 43 percent / BBr₃

2: K₂CO₃; Adogen 464 / acetone / Heating

With adogen 464; boron tribromide; potassium carbonate; In acetone;

DOI:10.1039/b615545f

Reference yield:

1-carbomethoxy-3,5-dihydroxybenzene (2150-44-9) → 1-bromo-3,5-bis(octyloxy)phenyl (937390-20-0)

Guidance literature:

Multi-step reaction with 4 steps

1: 96 percent / K₂CO₃; Adogen 464 / acetone / Heating

2: 86 percent / NaOH / methanol / Heating

3: SOCl₂ / 2 h / Heating

4: 0.70 g / CBrCl₃; 2-mercaptopyridine N-oxide sodium salt; AIBN / 1 h / Heating

With sodium hydroxide; thionyl chloride; adogen 464; 2,2'-azobis(isobutyronitrile); Bromotrichloromethane; 2-mercaptopyridine-1-oxide sodium salt; potassium carbonate; In methanol; acetone; 4: Barton decarboxylation;

DOI:10.1039/b615545f

upstream raw materials:

1-bromo-octane

5-bromoresorcinol

3,5-dioctylbenzoic acid chloride

1-carbomethoxy-3,5-dihydroxybenzene

Downstream raw materials:

3,5-dioctyloxybenzeneboronic acid ethylene glycol ester

Refernces

• 1、 -. "Organic fluorescent material for ultrahigh resolution cell imaging as well as preparation and application of organic fluorescent material". Paragraph 0030-0034; 0042-0047; 0053-0058. . Retrieved 2019/11/04.