1-Methylimidazolium chloride

Base Information

• Chemical Name: 1-Methylimidazolium chloride
• CAS No.: 35487-17-3
• Molecular Formula: C4H6 N2 . Cl H
• Molecular Weight: 118.566
• Hs Code.: 29332900
• European Community (EC) Number: 684-557-0
• DSSTox Substance ID: DTXSID60479995
• Mol file: 35487-17-3.mol

Synonyms:1-Methylimidazolium chloride;35487-17-3;1-Methylimidazole hydrochloride;1-methylimidazole;hydrochloride;1-methyl-1H-imidazole hydrochloride;n-methylimidazolium chloride;n-methylimidazole hydrochloride;DTXSID60479995;1-Methylimidazolium chloride, 95%;1-Methylimidazolium Chloride Quality;AKOS015912541;AS-79001;CS-0188308

Chemical Property of 1-Methylimidazolium chloride

Chemical Property:

• Vapor Pressure: 0.0499mmHg at 25°C
• Boiling Point: 231.7°C at 760 mmHg
• Flash Point: 118 °C
• PSA: 17.82000
• LogP: 1.22210
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 118.0297759
• Heavy Atom Count: 7
• Complexity: 44.8

Purity/Quality:

99% ^*data from raw suppliers

1-Methylimidazolium chloride 95% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xn
• Statements: 22-36/37/38
• Safety Statements: 26

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CN1C=CN=C1.Cl
• Uses: Basionic Ionic Liquids 1-Methylimidazolium chloride behaves as a solvent and catalyst during the formation of 5-hydroxymethylfurfural from fructose and sucrose via acid-catalyzed dehydration.

Technology Process of 1-Methylimidazolium chloride

There total 13 articles about 1-Methylimidazolium chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

1-methyl-1H-imidazole (616-47-7) + 2-methoxy-ethanol (109-86-4,95507-80-5) + methanesulfonyl chloride (124-63-0) → 2-methoxyethyl methanesulfonate (16427-44-4) + 1-methylimidazolium chloride (35487-17-3)

Guidance literature:

In dichloromethane; at 10 - 20 ℃; for 4h;

Reference yield:

benzoyl chloride (98-88-4) + β-naphthol (135-19-3) → 2-naphthyl benzoate (93-44-7) + 1-methylimidazolium chloride (35487-17-3)

Guidance literature:

With 1-methyl-1H-imidazole; In dichloromethane; at 25 ℃; Kinetics; Mechanism;

Reference yield:

1-acetyl-3-methyl-1H-imidazol-3-ium chloride (28712-12-1) + 4-nitro-aniline (100-01-6,104810-17-5) → N-(4-Nitrophenyl)acetamide (104-04-1) + 1-methylimidazolium chloride (35487-17-3)

Guidance literature:

In dichloromethane; at 25 ℃; Kinetics; Mechanism;

upstream raw materials:

trifluoroethylamine

1-tosyl-3-methyl-imidazolium chloride

3-amino-5-nitro-benzoic acid methyl ester

1-acetyl-3-methyl-1H-imidazol-3-ium chloride

Downstream raw materials:

N-methylimidazolium triflate

1-methylimidazole hydrogen sulfate

1-ethyl-3-methyl-1H-imidazol-3-ium chloride

1,3-dimethylimidazolium chloride

Refernces

• 1、 Monjoint, P.,Ruasse, M. F.. "Sulfonyl transfer from imidazoles". . p. 356 - 360. Retrieved 2007/10/02.
• 2、 Lapshin, S. A.,Dadali, V. A.,Litvinenko, L. M.,Simanenko, Yu. S.. "MECHANISM OF THE REACTION OF ACETYL HALIDES WITH AROMATIC AMINES IN THE PRESENCE OF N-SUBSTITUTED IMIDAZOLES". . p. 1730 - 1735. Retrieved 2007/10/02.