3,6-Caryolanediol

Base Information

• Chemical Name: 3,6-Caryolanediol
• CAS No.: 155485-76-0
• Molecular Formula: C₁₅H₂₆O₂
• Molecular Weight: 238.37
• Mol file: 155485-76-0.mol

Synonyms:Tricyclo[6.3.1.02,5]dodecane-1,9-diol,4,4,8-trimethyl-, [1R-(1a,2a,5b,8b,9b)]-; Caryolan-1,9b-diol; Caryolane-1,9b-diol

Chemical Property of 3,6-Caryolanediol

Chemical Property:

• PSA: 40.46000
• LogP: 2.72470

Purity/Quality:

98%min ^*data from raw suppliers

Caryolane-1,9β-diol 95+% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 3,6-Caryolanediol

There total 6 articles about 3,6-Caryolanediol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C22H32N2O3S → (β,9β)-caryolane-1,9-diol (155485-76-0)

Guidance literature:

Multi-step reaction with 3 steps

1: NaOMe

2: pyridine

3: (i) B₂H₆, (ii) aq. H₂O₂

With sodium methylate; In pyridine;

DOI:10.1021/jo00830a055

Reference yield:

Caryol-9-en-1-ol → (β,9β)-caryolane-1,9-diol (155485-76-0)

Guidance literature:

Multi-step reaction with 2 steps

1: pyridine

2: (i) B₂H₆, (ii) aq. H₂O₂

In pyridine;

DOI:10.1021/jo00830a055

Reference yield:

β-caryophyllene (87-44-5) → (β,9β)-caryolane-1,9-diol (155485-76-0)

Guidance literature:

With dihydrogen peroxide; vanadia; acetone;

upstream raw materials:

β-caryophyllene

Caryophyllene oxide

caryophyllene-1β,10α-epoxide

Downstream raw materials:

(1R,2S,5R,8S,9S)-1-hydroxy-9-acetoxycaryolane

Refernces

• 1、 Nisnevich, G. A.,Korchagina, D. V.,Makal'skii, V. I.,Dubovenko, Zh. V.,Barkhash, V. A.. "MOLECULAR REARRANGEMENTS OF CARYOPHYLLENE AND ISOCARYOPHYLLENE 4,5-EPOXIDES IN SUPERACIDIC MEDIA". . p. 441 - 453. Retrieved 2007/10/02.