(4S,2'S,3'R,6'S,7'S)-(-)-3-[9'-(tert-butyldiphenylsilyloxy)-2'-chloro-3'-hydroxy-6',7'-O-isopropylidenenonanoyl]-4-benzyloxazolidinone

Base Information Edit

Chemical Name:(4S,2'S,3'R,6'S,7'S)-(-)-3-[9'-(tert-butyldiphenylsilyloxy)-2'-chloro-3'-hydroxy-6',7'-O-isopropylidenenonanoyl]-4-benzyloxazolidinone
CAS No.:1089174-15-1
Molecular Formula:C₃₈H₄₈ClNO₇Si
Molecular Weight:694.34
Hs Code.:
Mol file:1089174-15-1.mol

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Chemical Property of (4S,2'S,3'R,6'S,7'S)-(-)-3-[9'-(tert-butyldiphenylsilyloxy)-2'-chloro-3'-hydroxy-6',7'-O-isopropylidenenonanoyl]-4-benzyloxazolidinone Edit

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Technology Process of (4S,2'S,3'R,6'S,7'S)-(-)-3-[9'-(tert-butyldiphenylsilyloxy)-2'-chloro-3'-hydroxy-6',7'-O-isopropylidenenonanoyl]-4-benzyloxazolidinone

There total 1 articles about (4S,2'S,3'R,6'S,7'S)-(-)-3-[9'-(tert-butyldiphenylsilyloxy)-2'-chloro-3'-hydroxy-6',7'-O-isopropylidenenonanoyl]-4-benzyloxazolidinone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: C₂₆H₃₆O₄Si

: 104324-16-5
(4S)-(+)-3-(chloroacetyl)-4-(phenylmethyl)-2-oxazolidinone

: 1089174-15-1
(4S,2'S,3'R,6'S,7'S)-(-)-3-[9'-(tert-butyldiphenylsilyloxy)-2'-chloro-3'-hydroxy-6',7'-O-isopropylidenenonanoyl]-4-benzyloxazolidinone

Guidance literature:: (4S)-(+)-3-(chloroacetyl)-4-(phenylmethyl)-2-oxazolidinone; With di-n-butylboryl trifluoromethanesulfonate; triethylamine; In dichloromethane; at -78 - 20 ℃; for 1h;

C₂₆H₃₆O₄Si; In dichloromethane; at -78 - 0 ℃; for 1.5h;

With dihydrogen peroxide; In methanol; dichloromethane; water; at 20 ℃; for 1h; aq. phosphate buffer;
DOI:10.1002/chem.200801024