K[Fe(III)(tBuTPP)(O₂^(2-))]

Base Information

• Chemical Name: K[Fe(III)(tBuTPP)(O₂^(2-))]
• CAS No.: 1352062-25-9
• Molecular Formula: C₆₀H₆₀FeN₄O₂*K
• Molecular Weight: 964.107
• Mol file: 1352062-25-9.mol

Synonyms:

Chemical Property of K[Fe(III)(tBuTPP)(O₂^(2-))]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of K[Fe(III)(tBuTPP)(O₂^(2-))]

There total 3 articles about K[Fe(III)(tBuTPP)(O₂^(2-))] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

potassium superoxide (12030-88-5) + chloro(5(4),10(4),15(4),20(4)-tetra-tert-butyl-5,10,15,20-tetraphenylporphyrinato)iron(III) trihydrate → K[Fe(III)(tBuTPP)(O2(2-))] (1352062-25-9)

Guidance literature:

With Bu₄NPF₆; 18-crown-6; In dimethyl sulfoxide; Electrolysis; under N2; Fe complex in dry DMSO electrochemically reduced in presence of Bu4NPF6 and 18-crown-6 (10-fold excess); satd. soln. of KO2 in DMSO added at 25°C; reversible react.; not isolated; monitored by UV-vis spectra; Kinetics;

DOI:10.1039/c1dt11521a

Reference yield:

iron tetrakis(p-tert-butylphenyl)porphyrin chloride (64413-51-0) → K[Fe(III)(tBuTPP)(O2(2-))] (1352062-25-9)

Guidance literature:

With potassium superoxide; In dimethyl sulfoxide;

DOI:10.1039/c1dt11521a

Reference yield:

potassium superoxide, (18)O-labeled (12030-88-5) + chloro(5(4),10(4),15(4),20(4)-tetra-tert-butyl-5,10,15,20-tetraphenylporphyrinato)iron(III) trihydrate → K[Fe(III)(tBuTPP)(O2(2-))] (1352062-25-9) + K[Fe(III)(5(4),10(4),15(4),20(4)-tetra-tert-butyl-5,10,15,20-tetraphenylporphyrinato)((18)O2)]

Guidance literature:

In dimethyl sulfoxide; K(18)O2 suspended in soln. of Fe complex in dry DMSO; stirred; soln. filtered under Ar; detd. by mass spectra;

DOI:10.1039/c1dt11521a

upstream raw materials:

potassium superoxide

potassium superoxide, ⁽¹⁸⁾O-labeled

iron tetrakis(p-tert-butylphenyl)porphyrin chloride

Refernces