102-46-5Relevant articles and documents
Improved preparation of 3,3′,4,4′-tetramethyldiphenylethane by self coupling reaciton in aqueous media
Hu, Yu-Lin,Lu, Ming,Liu, Qi-Fa,Ge, Qiang
, p. 1056 - 1063 (2009)
In this article, 3,3′,4,4′-tetramethyldiphenylethane was obtained in 86.5% total yield by self coupling reaction of 3,4-dimethylbenzyl chloride catalyzed by Cu/Cu/2/Cl/2//PEG-600 and promoted by iron in aqueous media and the starting
Mechanism of solvolysis of substituted benzyl chlorides in aqueous ethanol
Denegri, Bernard,Mati?, Mirela,Va?ko, Monika
supporting information, (2021/11/22)
The mechanism of solvolyses of activated ortho-, meta- and para-substituted benzyl chlorides in aqueous ethanol has been studied by using the Hammett-Brown and Yukawa-Tsuno treatments as well as by correlating logarithms of solvolysis rate constants with relative stabilities of corresponding benzyl carbocations in water calculated at the IEFPCM-M06–2X/6-311+G(3df,3pd) level of theory. Benzyl chlorides containing strong conjugative electron-donors in the para-position solvolyze by the SN1 mechanism, whereas other activated benzyl chlorides solvolyze by the SN2 mechanism via loose transition states.
BENZODIAZEPINONE COMPOUNDS AND METHODS OF TREATMENT USING SAME
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Page/Page column 65, (2011/04/19)
The invention provides 1,4-benzodiazepinone compounds, pharmaceutical compositions, and methods of treating autoimmune disorders, chronic inflammatory disorders, and hyperproliferative disorders. For example, the 1,4-benzodiazepinone compounds and pharmaceutical compositions are contemplated to be useful for treating rheumatoid arthritis, graft-versus-host disease, inflammatory bowel disease, and the like.
An inexpensive and convenient procedure for chloromethylation of aromatic hydrocarbons by phase transfer catalysis in aqueous media
Hu, Yu Lin,Lu, Ming,Ge, Qiang,Wang, Peng Cheng,Zhang, Sheng Bin,Lu, Ting Ting
experimental part, p. 97 - 102 (2010/08/05)
Reaction of aromatic hydrocarbons catalyzed by a novel catalytic system consisting of zinc chloride, acetic acid, sulfuric acid and PEG-800 in aqueous media under PTC conditions results in chloromethylation in good to excellent yield.