107701-35-9

Basic information

• Product Name: O-ethyl S-(4-chlorophenyl) thiocarbonate
• Synonyms: O-ethyl S-(4-chlorophenyl) thiocarbonate
• CAS NO: 107701-35-9
• Molecular Weight: 216.688
• Mol File: 107701-35-9.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: O-ethyl S-(4-chlorophenyl) thiocarbonate(CAS DataBase Reference)
• NIST Chemistry Reference: O-ethyl S-(4-chlorophenyl) thiocarbonate(107701-35-9)
• EPA Substance Registry System: O-ethyl S-(4-chlorophenyl) thiocarbonate(107701-35-9)

Safety Data

• Hazardous Substances Data: 107701-35-9(Hazardous Substances Data)

Upstream product

• 64-17-5 ethanol 
• 32315-10-9 bis(trichloromethyl) carbonate 
• 106-54-7 p-Chlorothiophenol 
• 1142-19-4 4,4'-dichlorodiphenyl disulfide 
• 201230-82-2 carbon monoxide 
• 541-41-3 chloroformic acid ethyl ester 

Downstream Products

• 444901-21-7 ethyl 3-chlorobenzylcarbamate 
• 17101-98-3 (4-methyl-benzyl)carbamic acid ethyl ester 
• 2621-78-5 ethyl N-benzylcarbamate 
• 35573-36-5 N-(4-methoxyphenylmethyl)carbamic acid ethyl ester 
• 51172-60-2 ethyl (4-chlorobenzyl)carbamate 
• 108-90-7 chlorobenzene 

Relevant articles and documents

Kinetics and mechanism of the aminolysis of O-ethyl S-aryl thiocarbonates in acetonitrile

The Kinetics and mechanism of the reactions of O-ethyl S-(Z)aryl thiocarbonates with (X)benzylamines in acetonitrile at 45.0 °C are studied. Relatively small values of βx (βnuc) = 0.6 to approximately 0.8 and βz (βlg) = -0.5 to approximately -0.7 together with a negative cross-interaction constant ρxz (= -0.47) and failure of the reactivity-selectivity principle (RSP) are interpreted to indicate a concerted mechanism. The normal kinetic isotope effects (kH/kD = 1.3 to approximately 1.8) involving deuterated benzylamine nucleophiles suggest a hydrogen-bonded, four-center-type transition state.

A new method for synthesis of S-aryl-O-alkyl thiolcarbonates: Selenium-catalyzed reaction of alcohols with carbon monoxide and diaryl disulfides

A unique catalytic ability of selenium has been developed. When alcohols were allowed to react with diaryl disulfides in the presence of a catalytic amount of selenium under a pressurized carbon monoxide, S-aryl-O-alkyl thiolcarbonates were obtained in moderate to good yields.