163849-82-9Relevant articles and documents
A solvent- and temperature-dependent intramolecular equilibrium of diamagnetic and paramagnetic states in Co complexes bearing triaryl amines
Schnaubelt, Linda,Petzold, Holm,Dmitrieva, Evgenia,Rosenkranz, Marco,Lang, Heinrich
supporting information, p. 13180 - 13189 (2018/10/02)
Complexes [Co(L)2](ClO4)2 (L = o-substituted 2-(pyridine-2-yl)-1,10-phenanthrolines 1a-c) containing three redox active centres (a Co2+ ion and two triaryl amine (Tara) units) have been synthesised. The order of
Design of new tetrazine-triphenylamine bichromophores - Fluorescent switching by chemical oxidation
Quinton, Cassandre,Alain-Rizzo, Valerie,Dumas-Verdes, Cecile,Clavier, Gilles,Miomandre, Fabien,Audebert, Pierre
, p. 1394 - 1403 (2012/04/17)
Original new fluorescent and electroactive compounds have been prepared, which feature two different fluorescent groups linked through an oxygen atom spacer. We describe here the synthesis, photophysical and electrochemical properties and their interplay, and our theoretical calculations. These molecules are composed of two fluorophores, an electron-rich triphenylamine unit and an electron-poor tetrazine unit. Although the bichromophores are not fluorescent in the neutral state due to a photoinduced electron transfer from the triphenylamine unit to the tetrazine unit, one can restore the fluorescence by oxydation of the triphenylamine moiety. Thus, a redox-fluorescent switch has been realized. Tetrazine-triphenylamine bichromophores linked by an oxygen atom were designed and synthesized. Their photophysical and electrochemical properties were investigated. These dyads are nonfluorescent compounds in their neutral state because of phoinduced electron transfer. However, tetrazine fluorescence was restored by chemical oxidation (cation radical formation). Copyright
EMISSIVE ARYL-HETEROARYL COMPOUNDS
-
, (2011/01/05)
Disclosed herein are compounds represented by Formula 1, wherein R1, Ar1, X, Ar2, Ara, and Het are described herein. Compositions and light-emitting devices related thereto are also disclosed.