16698-03-6

Basic information

• Product Name: Benzenamine, N-methyl-N,4-dinitro-
• CAS NO: 16698-03-6
• Molecular Formula: C7H7N3O4
• Molecular Weight: 197.15
• Mol File: 16698-03-6.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Benzenamine, N-methyl-N,4-dinitro-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, N-methyl-N,4-dinitro-(16698-03-6)
• EPA Substance Registry System: Benzenamine, N-methyl-N,4-dinitro-(16698-03-6)

Safety Data

• Hazardous Substances Data: 16698-03-6(Hazardous Substances Data)

Upstream product

• 100-15-2 N-methyl(p-nitroaniline) 
• 67-56-1 methanol 
• 20020-13-7 N,4-dinitroaniline 
• 74-88-4 methyl iodide 
• 943-41-9 N-methyl-N-nitroso-4-nitroaniline 
• 71-43-2 benzene 
• 1145-27-3 N,N’-dimethyl-N,N’-diphenylmethanediamine 
• 7697-37-2 nitric acid 
• 108-24-7 acetic anhydride 
• 56-23-5 tetrachloromethane 
• 4559-87-9 1-methyl-1-phenylurea 
• 7782-77-6 cis-nitrous acid 
• 64-19-7 acetic acid 
• 614-00-6 N-methyl-N-nitrosoaniline 

Downstream Products

• 92-93-3 1-phenyl-4-nitrobenzene 
• 2044-88-4 N-methyl-2,4-dinitroaniline 
• 100-15-2 N-methyl(p-nitroaniline) 
• 943-41-9 N-methyl-N-nitroso-4-nitroaniline 
• 19092-03-6 N-methyl-2,4-dinitro-N-nitroaniline 
• 58538-01-5 N-methyl-N-nitroso-2,4-dinitroaniline 

Relevant articles and documents

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Synthesis and properties of secondary N-nitroamines

Secondary arylamines and related compounds can readily be converted into the corresponding N-nitroamines by treatment of their organomagnesium derivatives with butyl nitrate. The yield of the products ranges from 45 to 77%. Secondary aromatic N-nitroamine

Photolysis of some N-nitroso- and N-nitro-anilines in solution

The photolyses of three N-methyl-N-nitrosoanilines and two N-methyl-N-nitroanilines in organic solvents have been studied in the range of 300-340 nm. The influence of solvent character and the presence or absence of oxygen play important roles in the product composition range. The primary photochemical process involves N-N fission, this being homolytic in aprotic solvents and heterolytic in methanol. Three novel mechanistic conclusions are proposed, namely photosolvolysis of a nitrosamine in methanol, photooxidation of nitrosamines in aprotic solvents and the production of biphenyl derivatives on photolysis of nitro-substituted nitrosamines and nitramines in aromatic solvents.