169897-96-5Relevant articles and documents
Rhizoxin synthetic studies. 1. Synthesis of the right hand [C(1) to C(9)]portion via a "pinwheel" approach
Lafontaine, Jennifer A.,Leahy, James W.
, p. 6029 - 6032 (1995)
A concise synthetic approach to the C(1) - C(9) fragment of the antitumor macrolide rhizoxin via a three-fold pseudosymmetric intermediate is described. The preparation (from readily available γ-butyrolactone) includes both an asymmetric allylation and an