2933-74-6

Basic information

• Product Name: Ethanol, 2-(4-methylphenyl)amino-
• Synonyms: Ethanol, 2-(4-methylphenyl)amino-;2-[(4-Methylphenyl)amino]ethanol
• CAS NO: 2933-74-6
• Molecular Formula: C₉H₁₃NO
• Molecular Weight: 151.21
• Mol File: 2933-74-6.mol
• Article Data: 30

Chemical Properties

• Melting Point: 42.5°C
• Boiling Point: 273.23°C (rough estimate)
• Flash Point: 140.541 °C
• Appearance: /
• Density: 1.0406 (rough estimate)
• Vapor Pressure: 0.00119mmHg at 25°C
• Refractive Index: 1.5675 (estimate)
• CAS DataBase Reference: Ethanol, 2-(4-methylphenyl)amino-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanol, 2-(4-methylphenyl)amino-(2933-74-6)
• EPA Substance Registry System: Ethanol, 2-(4-methylphenyl)amino-(2933-74-6)

Safety Data

• Hazardous Substances Data: 2933-74-6(Hazardous Substances Data)

Usage

Description

Ethanol, 2-(4-methylphenyl)amino-, also known as 2-p-Tolylaminoethanol, is an organic compound derived from 1,2-Ethylene Glycol (E890140). It is primarily used in the synthesis of various materials and has potential applications in different industries.

Uses

Used in Nanotechnology Industry:
Ethanol, 2-(4-methylphenyl)aminois used as a precursor in the synthesis of nanotubes (1) and nanocables (2), which have potential applications in various fields such as electronics, energy storage, and sensing.
Used in Textile Industry:
Ethanol, 2-(4-methylphenyl)aminois primarily used in the synthesis of polyester fibers, which are widely used in the production of textiles and clothing due to their durability and versatility.
Used in Packaging Industry:
Ethanol, 2-(4-methylphenyl)aminois also used in the synthesis of polyethylene terephthalate (PET) bottling products, which are commonly used for packaging beverages and other consumer goods.
Used in Chemical Research:
Ethanol, 2-(4-methylphenyl)aminois utilized in the study of phosphocholine membranes through the synthesis of polyethylene glycol (4), which can provide insights into the structure and function of biological membranes.
Used in Environmental and Food Contaminant Analysis:
Ethanol, 2-(4-methylphenyl)aminois listed as a Drinking Water Contaminant Candidate List 3 (CCL 3) compound by the United States Environmental Protection Agency (EPA). It is important for monitoring environmental and food contaminants to ensure public health and safety.

InChI:InChI=1/C9H13NO/c1-8-2-4-9(5-3-8)10-6-7-11/h2-5,10-11H,6-7H2,1H3

Upstream product

• 74552-28-6 N-(p-Tolyl)carbamidsaeure-β-chlorethylester 
• 26583-58-4 β-(2-methylphenoxy)ethylamine 
• 106-49-0 p-toluidine 
• 107-21-1 ethylene glycol 
• 624-31-7 4-tolyl iodide 
• 141-43-5 ethanolamine 
• 106-43-4 para-chlorotoluene 
• 5198-46-9 3-(4-methylphenyl)-2-oxazolidinone 
• 106-38-7 para-bromotoluene 
• 540-51-2 2-bromoethanol 
• 75-21-8 oxirane 
• 940-64-7 2-(4-methylphenoxy)acetic acid 
• 96-49-1 [1,3]-dioxolan-2-one 
• 52316-60-6 2-hydroxyethylchloramine 

Downstream Products

• 19853-56-6 2-phenyl-3-p-tolyl-[1,3,2]oxazaphospholidine 
• 3367-48-4 1,4-bis(4-methylphenyl)piperazine 
• 7732-18-5 water 
• 71472-58-7 3,4-dihydro-7-methyl-2H-1,4-benzoxazine 
• 1246521-07-2 C₁₁H₁₆N₂O₂ 
• 1246521-06-1 C₁₉H₂₂N₂O₄ 
• 1246519-10-7 C₂₀H₂₃N₅O₃ 
• 1246521-05-0 C₁₇H₁₉NO₃ 
• 62131-56-0 N-p-Tolyl-2-(p-nitrophenoxy)-ethylamin 
• 38201-24-0 N-(4-methylphenyl)aziridine 
• 80077-16-3 N,N-Dimethyl-N'-(3-p-tolyl-[1,3,2]oxazaphospholidin-2-yl)-benzene-1,4-diamine 
• 73901-66-3 N,N-di-p-tolyl-thiourea 

Relevant articles and documents

Porous polymeric ligand promoted copper-catalyzed C-N coupling of (hetero)aryl chlorides under visible-light irradiation

A porous polymeric ligand (PPL) has been synthesized and complexed with copper to generate a heterogeneous catalyst (Cu@PPL) that has facilitated the efficient C-N coupling with various (hetero)aryl chlorides under mild conditions of visible-light irradiation at 80 °C (58 examples, up to 99% yields). This method could be applied to both aqueous ammonia and substituted amines, and is compatible to a variety of functional groups and heterocycles, as well as allows tandem C-N couplings with conjunctive dihalides. Furthermore, the heterogeneous characteristic of Cu@PPL has enabled a straightforward catalyst separation in multiple times of recycling with negligible catalytic efficiency loss by simple filtration, affording reaction mixtures containing less than 1 ppm of Cu residue. [Figure not available: see fulltext.]

Visible light-mediated Smiles rearrangements and annulations of non-activated aromatics

We report the first examples of radical cation Smiles rearrangements. A series of aryloxy alkylamines underwent spontaneous reaction, with the amino group displacing theipso-alkoxy group through substitution, at ambient temperature and under photoactivation by visible light in the presence of an acridinium catalyst (5 mol%). The study was extended to 3-(2-methoxyphenyl)propan-1-amine derivatives, which lack an appropriateipsoleaving group. Here, efficient cyclisations resulted in displacement of the methoxy group and formation of tetrahydroquinolines.

METHODS FOR PREPARING BENZOXAZINES

A method is provided for preparing a compound / the method comprising carrying out the following reaction: Formula (i); Formula (ii) where: R10 is hydrogen or a hydroxy protecting group; PG is an amine protecting group; and q is 1 where PG is a