527-60-6Relevant articles and documents
Enhanced Photodecarboxylation of an Aryl Ester in Polyethylene Films
Mori, Tadashi,Inoue, Yoshihisa,Weiss, Richard G.
, p. 4661 - 4664 (2003)
(Matrix presented) Photodecarboxylation is the exclusive photoreaction of 2,4,6-trimethylphenyl (S)-2-methylbutanoate In unstretched high-density polyethylene films. The sole product, (S)-1-(2-methylpropyl)-2,4,6- trimethylbenzene, is formed with complete
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Lapkin,Schkljajew,Schkljajewa
, (1941)
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Wolf,Barnes
, p. 3441,3445 (1969)
Iodine promoted reduction of aromatic carbonyl compounds with phosphonic acid to access hydrocarbons
Deng, Jinfeng,Xiao, Jing,Wang, Xiaoyi,Luo, Huang,Jia, Zhicheng,Wang, Jie
, (2022/04/19)
A novel method for selective reduction of aromatic carbonyl compounds by phosphorus acid under metal-free conditions is achieved to produce the corresponding reduced products in good to excellent yields. By using H3PO3/I2 system, various aromatic ketones and aldehydes could be reduced to the corresponding hydrocarbons. Diketone compounds could also be reduced to the corresponding Z-alkenes. The protocol is low-cost and easily scaled up, which provides a simple and practical approach to access corresponding hydrocarbons.
Selective hydroxylation of aryl iodides to produce phenols under mild conditions using a supported copper catalyst
Auni, Anika,Ding, Guodong,Hao, Leiduan,Li, Tao,Li, Xiaoyu,Xu, Haiping,Zhang, Qiang
, p. 25348 - 25353 (2021/08/03)
Owing to the high activity and low-cost, copper-based catalysts are promising candidates for transforming aromatic halides to yield phenols. In this work, we report the selective hydroxylation of aromatic iodides to produce phenols using an atomically dispersed copper catalyst (Cu-ZnO-ZrO2) under mild reaction conditions. The reactions were conducted without the use of additional organic ligands, and the protection of an inert atmosphere environment is not required. The catalyst can be easily prepared, scalable, and is very efficient for a wide range of substrates. The catalytic reactions can be carried out with only 1.24 mol% Cu loading, which shows great potential in mass production.