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Bis(trimethylsilyl)sulfide

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Name

Bis(trimethylsilyl)sulfide

EINECS 222-201-4
CAS No. 3385-94-2 Density 0.837 g/cm3
PSA 25.30000 LogP 3.38940
Solubility Soluble in tetrahydrofuran and toluene. Hydrolyzes in water. Melting Point N/A
Formula C6H18SSi2 Boiling Point 159.4 °C at 760 mmHg
Molecular Weight 178.446 Flash Point 50.2 °C
Transport Information UN 1993 Appearance clear colorless to slightly yellow liquid
Safety 36/37/39-45 Risk Codes 10-23/24/25
Molecular Structure Molecular Structure of 3385-94-2 (BIS(TRIMETHYLSILYL) SULFIDE) Hazard Symbols ToxicT
Synonyms

Disilathiane,hexamethyl- (9CI);Disilthiane, hexamethyl- (6CI,7CI,8CI);Bis(trimethylsilyl)sulfide;Bis(trimethylsilyl)sulfur;Hexamethyldisilathiane;Hexamethyldisilthian;Hexamethyldisilthiane;Hexamethyldisilyl sulfide;Hexamethyldisilylthiane;NSC 252160;

Article Data 48

Bis(trimethylsilyl)sulfide Specification

The Bis(trimethylsilyl)sulfide, with the CAS registry number 3385-94-2, is also known as Bis(trimethylsilyl)sulfide. It belongs to the product categories of Sulfur Compounds (for Synthesis); Synthetic Organic Chemistry. Its EINECS number is 222-201-4. This chemical's molecular formula is C6H18SSi2 and molecular weight is 178.44. What's more, its IUPAC name is trimethyl(trimethylsilylsulfanyl)silane. It is stable at common pressure and temperature, and it should be sealed and stored in a cool, ventilated and dry place. What's more, it should be protected from light.

Physical properties of Bis(trimethylsilyl)sulfide are: (1)ACD/LogP: 3.53; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 3.53; (4)ACD/BCF (pH 5.5): 285.06; (5)ACD/KOC (pH 5.5): 1990; (6)#Freely Rotating Bonds: 2; (7)Polar Surface Area: 25.3 Å2; (8)Index of Refraction: 1.432; (9)Molar Refractivity: 55.27 cm3; (10)Molar Volume: 213 cm3; (11)Surface Tension: 18.1 dyne/cm; (12)Density: 0.837 g/cm3; (13)Flash Point: 50.2 °C; (14)Enthalpy of Vaporization: 37.97 kJ/mol; (15)Boiling Point: 159.4 °C at 760 mmHg; (16)Vapour Pressure: 3.25 mmHg at 25°C.

Preparation: this chemical can be prepared by chloro-trimethyl-silane by heating. This reaction will need reagent S(MgBr)2 and solvent tetrahydrofuran with the reaction time of 2 hours. The yield is about 85%.

Uses of Bis(trimethylsilyl)sulfide: it can be used to produce dimethyltrisulfane at the temperature of 60 °C. It will need solvent CHCl3 with the reaction time of 14 hours. The yield is about 72.8%.

When you are using this chemical, please be cautious about it as the following:
It is flammable. It is toxic by inhalation, in contact with skin and if swallowed. When using it, you need wear suitable protective clothing, gloves and eye/face protection. In case of accident or if you feel unwell seek medical advice immediately (show the label where possible).

You can still convert the following datas into molecular structure:
(1)Canonical SMILES: C[Si](C)(C)S[Si](C)(C)C
(2)InChI: InChI=1S/C6H18SSi2/c1-8(2,3)7-9(4,5)6/h1-6H3
(3)InChIKey: RLECCBFNWDXKPK-UHFFFAOYSA-N

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