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Name |
Cyclodecanone |
EINECS | 216-119-8 |
CAS No. | 1502-06-3 | Density | 0.886 g/cm3 |
PSA | 17.07000 | LogP | 3.08000 |
Solubility | N/A | Melting Point |
21-24 °C(lit.) |
Formula | C10H18O | Boiling Point | 232.1 °C at 760 mmHg |
Molecular Weight | 154.252 | Flash Point | 82.2 °C |
Transport Information | N/A | Appearance | N/A |
Safety | 26 | Risk Codes | 36 |
Molecular Structure | Hazard Symbols | Xi | |
Synonyms |
NSC 90293; |
Article Data | 68 |
Conditions | Yield |
---|---|
With nickel In benzene for 7h; Heating; | 98% |
With sodium bromate; 1-n-butyl-3-methylimidazolim bromide at 70℃; for 150h; | 88% |
With ferredoxin reductase; [2Fe–2S] ferredoxin; cytochrome P450 enzyme CYP101C1 In aq. buffer pH=7.4; Enzymatic reaction; | 25% |
cyclodecanone
Conditions | Yield |
---|---|
With triethyl borane; ytterbium(III) triflate; allyl-trimethyl-silane In tetrahydrofuran at 20℃; for 2h; Inert atmosphere; | 95% |
Conditions | Yield |
---|---|
79% | |
In not given IR, PMR, mass spectral data, GLC;; | 79% |
6-bromocyclododecanone
A
cyclodecanone
B
trans-decal-9-ol
C
cis-9-decalol
Conditions | Yield |
---|---|
With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride In benzene at 60℃; for 15h; | A 4% B 20% C 75% |
Conditions | Yield |
---|---|
With (phthalocyaninato)iron(II); zirconium phosphate; oxygen; hydroquinone; palladium dichloride In water; N,N-dimethyl-formamide at 20℃; under 760 Torr; for 3h; Wacker oxidation; | 51% |
cyclodecanone
Conditions | Yield |
---|---|
Stage #1: methyl cis-11-oxabicyclo[8.1.0]undecane-1-carboxylate With methanol; water; sodium hydroxide for 5h; Reflux; Stage #2: With hydrogenchloride; methanol; water for 1h; Reflux; | 47% |
Conditions | Yield |
---|---|
at 650℃; under 0.75006 - 3.00024 Torr; | 30% |
Multi-step reaction with 2 steps 1: 37 percent / iodine, yellow HgO / toluene / Heating 2: 12 percent / AIBN, tri-n-butyltin hydride / benzene / Heating View Scheme |
Conditions | Yield |
---|---|
With dihydrogen peroxide; vanadium phosphorus oxide In acetonitrile at 70℃; for 20h; | 28% |
With dihydrogen peroxide; iron(III) chloride In pyridine; acetic acid Mechanism; | |
With cis-VI(6,6'-Cl2bpy)2O2> In tetrachloromethane; acetonitrile at 20℃; for 0.5h; Oxidation; | 75 % Chromat. |
10-Iodo-dec-1-en-3-one
A
cyclodecanone
B
decan-3-one
C
dec-1-en-3-one
D
cycloeicosane-1,11-dione
Conditions | Yield |
---|---|
With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride In benzene for 3h; Heating; Yields of byproduct given; | A 15% B n/a C n/a D n/a |
With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride In benzene for 3h; Heating; Yield given. Yields of byproduct given; |
Conditions | Yield |
---|---|
With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride In benzene Heating; | A 12% B 6% |
With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride In benzene at 80℃; for 3h; | A 15 % Chromat. B 27 % Chromat. |
The Cyclodecanone is an organic compound with the formula C10H18O. The IUPAC name of this chemical is Cyclodecanone. With the CAS registry number 1502-06-3, it is also named as Cyclodecan-1-one. The product's categories are C10; Carbonyl Compounds; Ketones. Besides, it should be stored in a dry, well-ventilated, lightproof place.
Physical properties about Cyclodecanone are: (1)ACD/LogP: 3.02; (2)ACD/LogD (pH 5.5): 3.02; (3)ACD/LogD (pH 7.4): 3.02; (4)ACD/BCF (pH 5.5): 116.05; (5)ACD/BCF (pH 7.4): 116.05; (6)ACD/KOC (pH 5.5): 1045.89; (7)ACD/KOC (pH 7.4): 1045.89; (8)#H bond acceptors: 1; (9)Polar Surface Area: 17.07 Å2; (10)Index of Refraction: 1.444; (11)Molar Refractivity: 46.24 cm3; (12)Molar Volume: 173.9 cm3; (13)Polarizability: 18.33×10-24 cm3; (14)Surface Tension: 29.7 dyne/cm; (15)Density: 0.886 g/cm3; (16)Flash Point: 82.2 °C; (17)Enthalpy of Vaporization: 46.88 kJ/mol; (18)Boiling Point: 232.1 °C at 760 mmHg; (19)Vapour Pressure: 0.06 mmHg at 25 °C.
Uses of Cyclodecanone: it can be used to produce Cyclodecanone oxime at temperature of 20 °C. It will need reagents hydroxylamine; sodium acetate and solvent methanol with reaction time of 1 hour. The yield is about 98%.
When you are using this chemical, please be cautious about it as the following:
It is irritating to the eyes. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
You can still convert the following datas into molecular structure:
(1)InChI: InChI=1/C10H18O/c11-10-8-6-4-2-1-3-5-7-9-10/h1-9H2
(2)InChIKey: SXOZDDAFVJANJP-UHFFFAOYAD
(3)Std. InChI: InChI=1S/C10H18O/c11-10-8-6-4-2-1-3-5-7-9-10/h1-9H2
(4)Std. InChIKey: SXOZDDAFVJANJP-UHFFFAOYSA-N