Environmental Science and Technology p. 80 - 87 (1994)
Update date:2022-08-10
Topics:
Roth
Dakoji
Hughes
Carmody
The hydrogenolysis (hydrodechlorination) of a series of pure PCB congeners with sodium borohydride was studied. In the absence of nickel compounds, very little reaction occurred, but in the presence of solid Raney-type nickel or in the presence of a soluble Ni(0)triphenylphosphine complex, extensive hydrogenolysis occurred at ambient temperatures in DMF. The selectivity of one congener versus another was studied and found to be low. The selectivity for 2-, 3-, and 4-chloro displacement from di- and trichlorobiphenyls in the presence of Ni(0) complexes, however, was found to be high. The selectivities are interpreted with respect to the known mechanism of oxidative addition of aryl halides with Ni(0) complexes.
View MoreShandong Yaroma Perfumery Co., Ltd.
Contact:+86- 531- 88024598
Address:7-702 Caizhi Central, 59 Gong Ye South Road, Jinan City,250101, P. R. China
Tianjin Tensing Fine Chemical Research Develop Centre
Contact:86-022-23718576,13032267585
Address:2-2-201,13 Guiyuan road,Huayuan Industry district,Tianjin,china
Jinan Jinguilin Chemical Co.,Ltd
Contact:+86-531-81188412
Address:3rd floor of Torch Building, Huanyuan Rd, City of Jinan
JOY (TIANJIN) TECHNOLOGY AND DEVELOPMENT CO., LTD.
Contact:+86-22-66666666
Address:Tianjin
Wuhan Better Organic Technology Inc.
Contact:13307163183
Address:Wuhan Economic&Technology Development Zone, Hubei
Doi:10.1039/c8dt02168f
(2018)Doi:10.1002/ejoc.201500685
(2015)Doi:10.1016/j.dyepig.2015.01.008
(2015)Doi:10.3390/molecules25122755
(2020)Doi:10.1002/cplu.201600099
(2016)Doi:10.2174/157017812800221717
(2012)