Diphenyl trithiocarbonate

Base Information

• Chemical Name: Diphenyl trithiocarbonate
• CAS No.: 2314-54-7
• Molecular Formula: C13H10S3
• Molecular Weight: 262.42
• NSC Number: 157932
• DSSTox Substance ID: DTXSID50945816
• Nikkaji Number: J142.393B
• Wikidata: Q82923264
• Mol file: 2314-54-7.mol

Synonyms:Diphenyl trithiocarbonate;Phenyl trithiocarbonate;bis(phenylsulfanyl)methanethione;2314-54-7;Carbonotrithioic acid, diphenyl ester;Diphenyl carbonotrithioate;SCHEMBL3073488;DTXSID50945816;UHXNHMBEGXLRMF-UHFFFAOYSA-N;NSC157932;NSC-157932;Carbonic acid, trithio-, diphenyl ester;AB-131/40897085

Chemical Property of Diphenyl trithiocarbonate

Chemical Property:

• Vapor Pressure: 3.35E-07mmHg at 25°C
• Refractive Index: 1.721
• Boiling Point: 430.1 °C at 760 mmHg
• Flash Point: 213.9 °C
• PSA: 82.69000
• Density: 1.31 g/cm³
• LogP: 4.85590
• XLogP3: 5.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 4
• Exact Mass: 261.99446384
• Heavy Atom Count: 16
• Complexity: 193

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)SC(=S)SC2=CC=CC=C2

Technology Process of Diphenyl trithiocarbonate

There total 17 articles about Diphenyl trithiocarbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

carbon disulfide (75-15-0,12122-00-8) + iodobenzene (591-50-4) → trithiocarbonic acid diphenyl ester (2314-54-7)

Guidance literature:

carbon disulfide; With sodium sulfide; In N,N-dimethyl-formamide; at 20 ℃; for 0.25h;

iodobenzene; With copper(II) ferrite; In N,N-dimethyl-formamide; at 100 ℃; for 12h; Catalytic behavior;

DOI:10.1016/j.molcata.2014.02.006

Reference yield: 86.0%

carbon disulfide (75-15-0,12122-00-8) + toluene-4-sulfonic acid phenyl ester (640-60-8) → trithiocarbonic acid diphenyl ester (2314-54-7)

Guidance literature:

carbon disulfide; With sodium sulfide; In N,N-dimethyl-formamide; at 20 ℃; for 0.25h;

toluene-4-sulfonic acid phenyl ester; With copper(l) iodide; In N,N-dimethyl-formamide; at 100 ℃; for 10h;

DOI:10.1002/ejoc.201201126

Reference yield: 82.0%

carbon disulfide (75-15-0,12122-00-8) + Phenyl triflate (17763-67-6) → trithiocarbonic acid diphenyl ester (2314-54-7)

Guidance literature:

carbon disulfide; With sodium sulfide; In N,N-dimethyl-formamide; at 20 ℃; for 0.25h;

Phenyl triflate; With copper(l) iodide; In N,N-dimethyl-formamide; at 100 ℃; for 10h;

DOI:10.1002/ejoc.201201126

upstream raw materials:

phenyl chlorodithioformate

sodium thiophenolate

thiophosgene

thiophenol

Downstream raw materials:

3-phenyl-5,5-bis(phenylthio)-1,4,2-oxathiazole

tetrakis(phenylthio)ethene

Ethyl phenyl sulfide

Z-1,2-bis(ethylthio)-1,2-bis(phenylthio)ethylene

Refernces

• 1、 Gholinejad, Mohammad,Karimi, Babak,Mansouri, Fariborz. "Synthesis and characterization of magnetic copper ferrite nanoparticles and their catalytic performance in one-pot odorless carbon-sulfur bond formation reactions". . p. 20 - 27. Retrieved 2014/03/21.
• 2、 Mizhiritskii, M. D.,Reikhsfel'd, V. O.. "SYNTHESIS OF ORGANIC SULFUR COMPOUNDS BY MEANS OF SILICON-CONTAINING REAGENTS". . p. 1373 - 1382. Retrieved 2007/10/02.