METHYL 2-BROMODECANOATE

Base Information

• Chemical Name: METHYL 2-BROMODECANOATE
• CAS No.: 7357-56-4
• Molecular Formula: C11H21BrO2
• Molecular Weight: 265.191
• Mol file: 7357-56-4.mol

Synonyms:DL-2-Bromodecanoicacid methyl ester;Methyl 2-bromodecanoate;Methyl a-bromodecanoate;NSC 29654;

Chemical Property of METHYL 2-BROMODECANOATE

Chemical Property:

• Boiling Point: 258.1 °C at 760 mmHg
• Flash Point: 122.2 °C
• PSA: 26.30000
• Density: 1.167 g/cm³
• LogP: 3.67350

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of METHYL 2-BROMODECANOATE

There total 7 articles about METHYL 2-BROMODECANOATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.0%

methanol (67-56-1) + ((Z)-1-Chloro-dec-1-enylsulfanyl)-benzene (117135-10-1) → methyl ester of α-bromodecanoic acid (7357-56-4)

Guidance literature:

With bromine; at -45 ℃; for 2h;

Reference yield: 53.0%

methanol (67-56-1) + caprinaldehyde (112-31-2) → Methyl decanoate (110-42-9) + methyl ester of α-bromodecanoic acid (7357-56-4)

Guidance literature:

caprinaldehyde; With ammonium cerium (IV) nitrate; lithium bromide; In neat liquid;

methanol; In neat liquid; at 35 - 40 ℃; for 3.5h;

DOI:10.1016/j.tetlet.2016.12.036

Reference yield:

n-decanoyl chloride (112-13-0) → methyl ester of α-bromodecanoic acid (7357-56-4)

Guidance literature:

With bromine; at 110 ℃; und anschliessend Behandeln mit Methanol;

upstream raw materials:

2-bromodecanoic acid

n-decanoyl chloride

methanol

α-bromodecanoyl chloride

Refernces

• 1、 Fortes, C. C.,Chaves, M. H.. "SOLVOLYSIS OF 1-CHLORO-1-ALKENYL PHENYL SULFIDES. SYNTHESIS OF α-BROMO PHENYL THIOCARBOXYLIC ESTERS, α-BROMO ALKYL CARBOXYLIC ESTERS AND α-PHENYLTHIO METHYL CARBOXYLIC ESTERS". . p. 751 - 762. Retrieved 2007/10/02.