Deacetylxylopic acid

Base Information

• Chemical Name: Deacetylxylopic acid
• CAS No.: 6619-95-0
• Molecular Formula: C20H30O3
• Molecular Weight: 318.45
• Mol file: 6619-95-0.mol

Synonyms:Deacetylxylopic acid

Chemical Property of Deacetylxylopic acid

Chemical Property:

• PSA: 57.53000
• LogP: 4.01090

Purity/Quality:

98% ^*data from raw suppliers

Deacetylxylopicacid 95+% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Deacetylxylopic acid

There total 12 articles about Deacetylxylopic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

15β–acetoxy–(–)–kaur–16–en–l9–oic acid (6619-97-2) → 15-β-hydroxy-ent-kaur-16-en-19-oic acid (6619-95-0)

Guidance literature:

With potassium hydroxide; In methanol; for 6h; Reflux;

DOI:10.5935/0103-5053.20150287

Reference yield: 57.0%

kaurenoic acid → 15-β-hydroxy-ent-kaur-16-en-19-oic acid (6619-95-0)

Guidance literature:

With selenium(IV) oxide; In 1,4-dioxane; at 20 ℃; for 2h; Inert atmosphere;

DOI:10.1016/j.ejmech.2013.05.010

Reference yield:

ent-15α-acetoxy-kaur-16-en-19-oic acid (6619-97-2,22343-40-4,73864-05-8) → ent-15α-hydroxy-kaur-16-en-19-oic acid (6619-95-0,22338-69-8,24573-07-7,112419-30-4)

Guidance literature:

With potassium hydroxide; In methanol; at 20 ℃;

DOI:10.1016/j.phytochem.2007.07.025

upstream raw materials:

ent-15α-acetoxy-kaur-16-en-19-oic acid

15α-Acetoxy-Δ¹⁶-kauren-18α-saeure

kaurenoic acid

15β–acetoxy–(–)–kaur–16–en–l9–oic acid

Downstream raw materials:

methyl ent-15-oxokaur-16-en-19-oate

Refernces

• 1、 Barrero,Oltra,Cerda-Olmedo,Avalos,Justicia. "Microbial transformation of ent-kaurenoic acid and its 15-hydroxy derivatives by the SG138 mutant of Gibberella fujikuroi". . p. 222 - 225. Retrieved 2001.
• 2、 Cheng, Dong-Liang,Cao, Xiao-Ping,Cheng, Jie-Kai,Roeder, E.. "DITERPENE GLYCOSIDES FROM SENECIO RUFUS". . p. 151 - 154. Retrieved 1993.
• 3、 De Santos, Juliana O.,Pereira, Guilherme R.,Brand?o, Geraldo C.,Borgati, Tatiane F.,Arantes, Lucas M.,De Paula, Renata C.,Soares, Luciana F.,Do Nascimento, Maria F.A.,Ferreira, Marlia R.C.,Taranto, Alex G.,Varotti, Fernando P.,De Oliveira, Alaíde B.. "Synthesis, in vitro antimalarial activity and in silico studies of hybrid kauranoid 1,2,3-Triazoles Derived from Naturally Occurring Diterpenes". . p. 551 - 565. Retrieved 2016/03/19.