cis-4-Isopropylcyclohexylmethanol

Base Information

• Chemical Name: cis-4-Isopropylcyclohexylmethanol
• CAS No.: 13828-37-0
• Molecular Formula: C10H20 O
• Molecular Weight: 156.268
• Mol file: 13828-37-0.mol

Synonyms:p-Menthan-7-ol,cis- (8CI); cis-Tetrahydroperillyl alcohol; cis-p-Menthan-7-ol

Chemical Property of cis-4-Isopropylcyclohexylmethanol

Chemical Property:

• Vapor Pressure: 0.019mmHg at 25°C
• Boiling Point: 223.666°C at 760 mmHg
• PKA: 15.05±0.10(Predicted)
• Flash Point: 97.198°C
• PSA: 20.23000
• Density: 0.882g/cm³
• LogP: 2.44110

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cis-4-Isopropylcyclohexylmethanol

There total 15 articles about cis-4-Isopropylcyclohexylmethanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4-(1-methoxy-1-methylethyl)-benzaldehyde → (E)-(4-isopropylcyclohexyl)methanol (13674-19-6) + (Z)-(4-isopropylcyclohexyl)methanol (13828-37-0)

Guidance literature:

With hydrogen; In tetrahydrofuran; at 160 ℃; for 20h; under 150015 Torr;

Reference yield:

(4-isopropylbenzaldehyde) (122-03-2) → (E)-(4-isopropylcyclohexyl)methanol (13674-19-6) + (Z)-(4-isopropylcyclohexyl)methanol (13828-37-0)

Guidance literature:

With hydrogen; Catalyst C; at 110 - 125 ℃; under 150015 Torr; Product distribution / selectivity;

Reference yield:

perillol (536-59-4) → (E)-(4-isopropylcyclohexyl)methanol (13674-19-6) + (Z)-(4-isopropylcyclohexyl)methanol (13828-37-0)

Guidance literature:

With hydrogen; In isopropyl alcohol; at 80 ℃; for 6h; under 75007.5 Torr; Overall yield = 94.6 %Chromat.; Autoclave;

DOI:10.1007/s11164-012-0527-8

upstream raw materials:

4-isopropylcyclohexane-1-carbaldehyde

aluminum isopropoxide

isopropyl alcohol

cis-p-menthanoic acid-⁽⁷⁾-ethyl ester

Downstream raw materials:

7-(3.5-dinitro-benzoyloxy)-cis-p-methane

Refernces

• 1、 ?tekrová, Martina,Paterová-Dudková, Iva,Vysko?ilová-Leitmannová, Eli?ka,?erveny, Libor. "Preparation and utilization of perillyl acetate". . p. 2075 - 2084. Retrieved 2013/02/22.
• 2、 -. "PROCESS FOR PREPARING 4-ISOPROPYLCYCLOHEXYLMETHANOL". Page/Page column 9. . Retrieved 2011/09/16.