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Name |
Zinc dimethyldithiocarbamate |
EINECS | 205-288-3 |
CAS No. | 137-30-4 | Density | 1.66 g/cm3 |
PSA | 134.68000 | LogP | 1.52290 |
Solubility | water: 0.0065 g/100 mL | Melting Point |
248-257 °C(lit.) |
Formula | C6H12N2S4Zn | Boiling Point | 129.4 °C at 760 mmHg |
Molecular Weight | 305.829 | Flash Point | 32 °C |
Transport Information | UN 2811 6.1/PG 2 | Appearance | Odorless white powder |
Safety | 22-26-28-36/37/39-45-60-61 | Risk Codes | 22-26-37-41-43-48/22-50/53 |
Molecular Structure | Hazard Symbols | T+,N | |
Synonyms |
Corona Corozate;Cuman;Cuman L;Eptac 1;Fuclasin-Ultra;Fulasin;Hermat ZDM;Hexazir;Mezene;Milbam;Molurame;Nocceler PZ;Orchard brand Ziram;Pomarzol Z-forte;Rhodiacid;Sanceler PZ;SoxinalPZ;Trikagol;Ultra Zinc DMC;VulkacitL;Z 75;ZDMC;ZDMC 80;Zerlate;Zimate;Zincbis(dimethyldithiocarbamate);Ziradin;Ziram;Zirberk;Ziride;Zirol;Zirthane;ZnMDC;Zinc, bis(dimethyldithiocarbamato)-(8CI);Aaprotect;Aavolex;Aazira;Accelerator L;Ancazate ME;Carbamodithioic acid, dimethyl-, zinc salt; |
Article Data | 5 |
Conditions | Yield |
---|---|
In acetonitrile Electrolysis; 4 h, initial voltage 10 V, Zn anode; product was collected, washed with acetonitrile and then petroleum ether and dried in vacuo; elem. anal.; | >99 |
zinc(II) chloride
sodium dimethyldithiocarbamate
bis(dimethylcarbamodithioato-κS,κS')zinc(II)
Conditions | Yield |
---|---|
In water byproducts: NaCl; ZnCl2, the thiocarbamate in water, immediately pptn.; filtered hot to remove NaCl and any excess of unreacted thiocarbamate, dried (vac. at 80°C), recrystn. (boiling benzene); | |
In ethanol ZnCl2 is dissolved in the minimum quantity of ethanol; addn. of a saturated ethanolic soln. of organic compound.; pptn., filtn., washing (ethanol); | |
In water |
carbon disulfide
dimethyl amine
zinc(II) chloride
bis(dimethylcarbamodithioato-κS,κS')zinc(II)
Conditions | Yield |
---|---|
In acetone direct reaction of ZnCl2 with dimethylamine and carbon disulfide in acetone; |
bis(dimethylcarbamodithioato-κS,κS')zinc(II)
tetra(n-butyl)ammonium benzoxazole-2-thiolate
Conditions | Yield |
---|---|
In acetone refluxed for 2 h; cooled, filtered, light petroleum added, crystals filtered off, washed with light petroleum, air dried; elem anal.; | 100% |
bis(dimethylcarbamodithioato-κS,κS')zinc(II)
tetra(n-butyl)ammonium benzothiazole-2-thiolate
tetra-n-butylammonium (benzothiazole-2-thiolato)bis(dimethyldithiocarbamato)zincate
Conditions | Yield |
---|---|
In acetone refluxed for 1 h; soln. filtered, filtrate partialy evapd., crystals filtered off, recrystd. from ethanol-light petroleum; elem anal.; | 100% |
Conditions | Yield |
---|---|
In toluene Zn-complex dissolved in toluene, ligand added, refluxed for 18 h, cooledto room temp.; filtered, evapd. to dryness, washed with Et2O; elem. anal.; | 82% |
bis(dimethylcarbamodithioato-κS,κS')zinc(II)
(S)-(-)-ethyl mandelate
Conditions | Yield |
---|---|
With triphenylphosphine; diethylazodicarboxylate In toluene at 2 - 20℃; for 17h; | 81% |
bis(dimethylcarbamodithioato-κS,κS')zinc(II)
{(CH3CH2CH2CH2)4N}(1+)*{S2COC2H5}(1-)={(CH3CH2CH2CH2)4N}{S2COC2H5}
Conditions | Yield |
---|---|
In acetone addn. of solid (Zn(S2CNMe2)2) in small portions to a soln. of (N-n-Bu4)(S2COEt) in acetone (room temp.), stirring (2 h); filtration, addn. of light petroleum (b.p. 60-80°C), refrigeration (0°C, 2 d), crystn., suction filtration in air, drying, recrystn. (light petroleum/acetone (1:1), room temp.); elem. anal.; | 80% |
2-ethyl-4,5-dihydrooxazole
bis(dimethylcarbamodithioato-κS,κS')zinc(II)
Conditions | Yield |
---|---|
In toluene Zn-complex dissolved in toluene, ligand added, refluxed for 23 h, cooledto room temp.; filtered, evapd., digested in CH2Cl2, filtered, evapd. to dryness; elem.anal.; | 40% |
bis(dimethylcarbamodithioato-κS,κS')zinc(II)
3-chloro-benzenecarboperoxoic acid
Zn(N,N-dimethyldithiocarbamato)(O-dmDTC)
Conditions | Yield |
---|---|
In chloroform; acetonitrile a soln. of ClC6H4CO3H in CHCl3/MeCN added dropwise to a soln. of Zn complex in CHCl3 at 4°C, stirred for 10-12 h; evapd. (vac.), washed (cold MeCN); elem. anal.; | 34% |
The Zinc dimethyldithiocarbamate , with cas registry number of 137-30-4, has other registry numbers including (1)111922-61-3 ; (2)12768-61-5 ; (3)12773-04-5 ; (4)14459-91-7 ; (5)14460-20-9 ; (6)17125-91-6 ; (7)19488-81-4 ; (8)31300-71-7 ; (9)50933-80-7 ; (10)55870-88-7 ; (11)8059-74-3 ; (12)8070-07-3 ; (13)98391-07-2. The chemical belongs to the categories of (1)Organometallics; (2)Analytical Chemistry; (3)Classes of Metal Compounds; (4)Environmental Endocrine Disruptors; (5)Transition Metal Compounds; (6)Zn (Zinc) Compounds; (7)Alphabetic; (8)European Community: ISO and DIN; (9)Fungicides; (10)Pesticides; (11)ZMethod Specific. Its IUPAC name is called zinc N,N-dimethylcarbamodithioate . The systematic name is zinc bis(dimethylcarbamodithioate) .
Physical properties of Zinc dimethyldithiocarbamate are: (1) ACD/LogP: 0.75 ; (2) # of Rule of 5 Violations: 0 ; (3) ACD/LogD (pH 5.5): -1.06 ; (4) ACD/LogD (pH 7.4): -2.68 ; (5) ACD/BCF (pH 5.5): 1 ; (6) ACD/BCF (pH 7.4): 1 ; (7) ACD/KOC (pH 5.5): 1 ; (8) ACD/KOC (pH 7.4): 1 ; (9) #H bond acceptors: 1 ; (10) #H bond donors: 0 ; (11) #Freely Rotating Bonds: 0 ; (12) Flash Point: 32 °C; (13) Enthalpy of Vaporization: 36.7 kJ/mol ; (14) Boiling Point: 129.4 °C at 760 mmHg ; (15) Vapour Pressure: 10.2 mmHg at 25°C ; (16) Appearance: odorless white powder.
When you are using this chemical, please be cautious about it as the following:
It is harmful if swallowed, very toxic by inhalation, and irritating to respiratory system. It is also very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Wear suitable protective clothing, gloves and eye/face protection. After contact with skin, wash immediately with plenty of soap-suds. Do not breathe dust. If contact with eyes accidently, rinse immediately with plenty of water and seek medical advice. Or if you feel unwell, seek medical advice immediately (show the label whenever possible.). This material and its container must be disposed of as hazardous waste. Avoid release to the environment. It should be stored at APPROX 4°C.
You can still convert the following datas into molecular structure:
(1) SMILES:[Zn+2].S=C([S-])N(C)C.[S-]C(=S)N(C)C;
(2) InChI:InChI=1/2C3H7NS2.Zn/c2*1-4(2)3(5)6;/h2*1-2H3,(H,5,6);/q;;+2/p-2;
(3) InChIKey:DUBNHZYBDBBJHD-NUQVWONBAT
The toxicity data is as follows:
Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
---|---|---|---|---|---|
bird - wild | LD50 | oral | 100mg/kg (100mg/kg) | Toxicology and Applied Pharmacology. Vol. 21, Pg. 315, 1972. | |
guinea pig | LD50 | oral | 200mg/kg (200mg/kg) | Farmakologiya i Toksikologiya Vol. 32, Pg. 356, 1969. | |
guinea pig | LDLo | intraperitoneal | 30mg/kg (30mg/kg) | BEHAVIORAL: COMA | Journal of the American Pharmaceutical Association, Scientific Edition. Vol. 41, Pg. 662, 1952. |
mammal (species unspecified) | LD50 | unreported | 1400mg/kg (1400mg/kg) | "Chemistry of Pesticides," Melnikov, N.N., New York, Springer-Verlag New York, Inc., 1971Vol. -, Pg. 213, 1971. | |
mouse | LC50 | inhalation | > 1056mg/m3/2H (1056mg/m3) | SENSE ORGANS AND SPECIAL SENSES: CORNEAL DAMAGE: EYE BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) LUNGS, THORAX, OR RESPIRATION: DYSPNEA | Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 12(4), Pg. 12, 1968. |
mouse | LD50 | intraperitoneal | 15500ug/kg (15.5mg/kg) | Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. Vol. 17, Pg. S155, 1992. | |
mouse | LD50 | intravenous | 18mg/kg (18mg/kg) | U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#04886, | |
mouse | LD50 | oral | 480mg/kg (480mg/kg) | BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) BEHAVIORAL: CHANGES IN MOTOR ACTIVITY (SPECIFIC ASSAY) | Farmakologiya i Toksikologiya Vol. 28, Pg. 230, 1965. |
mouse | LD50 | subcutaneous | 309mg/kg (309mg/kg) | Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. Vol. 17, Pg. S155, 1992. | |
rabbit | LD50 | oral | 400mg/kg (400mg/kg) | Pesticide Chemicals Official Compendium, Association of the American Pesticide Control Officials, Inc., 1966. Vol. -, Pg. 1250, 1966. | |
rabbit | LD50 | skin | > 2gm/kg (2000mg/kg) | United States Environmental Protection Agency, Office of Pesticides and Toxic Substances. Vol. 8EHQ-1090-1045, | |
rabbit | LDLo | intraperitoneal | 50mg/kg (50mg/kg) | BEHAVIORAL: COMA | Journal of the American Pharmaceutical Association, Scientific Edition. Vol. 41, Pg. 662, 1952. |
rat | LC50 | inhalation | 26mg/m3/2H (26mg/m3) | National Technical Information Service. Vol. OTS0540394, | |
rat | LD50 | intraperitoneal | 8700ug/kg (8.7mg/kg) | Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. Vol. 17, Pg. S155, 1992. | |
rat | LD50 | oral | 267mg/kg (267mg/kg) | United States Environmental Protection Agency, Office of Pesticides and Toxic Substances. Vol. 8EHQ-1090-1045, | |
rat | LD50 | skin | > 6gm/kg (6000mg/kg) | Farm Chemicals Handbook. Vol. -, Pg. C329, 1991. | |
rat | LD50 | subcutaneous | 69mg/kg (69mg/kg) | Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. Vol. 17, Pg. S155, 1992. | |
rat | LD50 | unreported | 1230mg/kg (1230mg/kg) | Environmental Quality and Safety, Supplement. Vol. 3, Pg. 618, 1975. |