10196-30-2Relevant articles and documents
Electroorganic chemistry; 145: Coupling reaction of an olefin with a radical NO.3 generated by anodic oxidation of NO-3
Shono,Chuankamnerdkarn,Maekawa,Ishifune,Kashimura
, p. 895 - 897 (1994)
When NO-3 is electrochemically oxidized in the presence of a variety of terminal and 1,2-disubstituted olefins 1 in a mixed solvent system (MeCN:H2O:Et2O = 10:2:1), a radical NO.3 is generated from NO-3 and nitrate esters 3 are formed by a new coupling reaction of the olefin with the radical. The products 3 can be further transformed into the corresponding alcohols 4 and alkyl iodides 5. Under the same reaction conditions, 1,1-di- and 1,1,2-trisubstituted olefins 6 do not give nitrate esters but afford oxazoline derivatives 7. (1S,5S)-(-)-β-Pinene (13) is diastereoselectively transformed into (1S,2R,5S)-(-)-myrtanol (14) by this technique.
Palladium-catalyzed ring opening of isoprene monoxide with nitrogen nucleophiles - Asymmetric synthesis of branched amino sugars
Trost, Barry M.,Jiang, Chunhui,Hammer, Kristin
, p. 3335 - 3345 (2007/10/03)
The Pd-catalyzed regio- and enantioselective ring opening of isoprene monoxide with primary amines as pronucleophiles is developed with good yield and enantioselectivity, constructing a quaternary stereocenter enantioselectively. This methodology was used
The use of alpha-amino acids in the synthesis of derivatives of 2-aminoethanethiol as potential antiradiation agents.
Piper,Stringfellow Jr.,Johnston
, p. 911 - 920 (2007/10/05)
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