104224-68-2Relevant articles and documents
High-performance intrinsic low-k polymer via the synergistic effect of its three units: Adamantyl, perfluorocyclobutylidene and benzocyclobutene
Kong, Lingqiang,Qi, Tianke,Ren, Zhidong,Jin, Yunxia,Li, Yan,Cheng, Yuanrong,Xiao, Fei
, p. 68560 - 68567 (2016)
Perfluorocyclobutylidene (PFCB) polymers have gained much interest as the next generation fluoropolymers due to their low dielectric constant, low surface energy, thermal and thermal oxidative stability and chemical resistance. Herein, we obtained a low-k
A transition metal complex compound, and the compound of the catalyst and a catalyst for large amt. pentavelent carried out in the presence of an olefin multimer manufacturing method
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Paragraph 0187, (2017/07/01)
PROBLEM TO BE SOLVED: To provide a transition metal complex compound, an olefin multimerization catalyst having excellent activity and containing the same and a method for producing an olefin multimer carried out in the presence of the catalyst.SOLUTION: This transition metal complex compound is one having a phenoxyimine ligand and this olefin multimerization catalyst contains following component (A) and component (B). (A) is the transition metal compound and (B) is a compound selected from the group consisting of an organic metal compound (B-1), an organic aluminumoxy compound (B-2) and a compound (B-3) forming an ion pair by reacting with the transition metal compound (A).
New synthesis of 6[3-(1-adamantyl)-4-methoxyphenyl]-2-naphthoic acid and evaluation of the influence of adamantyl group on the DNA binding of a naphthoic retinoid
Milanese, Alberto,Gorincioi, Elena,Rajabi, Mehdi,Vistoli, Giulio,Santaniello, Enzo
scheme or table, p. 151 - 158 (2011/11/07)
6[3-(1-Adamantyl)-4-methoxyphenyl]-2-naphthoic acid (Adapalene), a synthetic aromatic retinoid specific for RARβ and RARγ receptors, has been prepared utilizing a Pd/C-mediated Suzuki coupling between 6-bromo-2-naphthoic acid and 4-methoxyphenyl boronic acid, followed by introduction of an adamantyl group in the position 3 of the formed 6-(4-methoxyphenyl)-2-naphthoic acid. The interaction of 6-(4-methoxyphenyl)-2- naphthoic acid/ethyl ester and the 3-adamantyl analogs with DNA was studied in aqueous solution at physiological conditions by UV-vis spectroscopy. The calculated binding constants Kligand-DNA ranged between 1.1 × 104 M-1 and 1.1 × 105 M-1, the higher values corresponding to those of the adamantylated compounds. Molecular modeling studies have emphasized that the intercalative binding of adapalene and its derivatives to DNA is mainly stabilized by hydrophobic interactions related to the presence of the adamantyl group.