1609939-35-6

Basic information

• Product Name: 2-methoxy-8-methyl-3-phenylisoquinolin-1(2H)-one
• Synonyms: 2-methoxy-8-methyl-3-phenylisoquinolin-1(2H)-one
• CAS NO: 1609939-35-6
• Molecular Weight: 265.312
• Mol File: 1609939-35-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-methoxy-8-methyl-3-phenylisoquinolin-1(2H)-one(CAS DataBase Reference)
• NIST Chemistry Reference: 2-methoxy-8-methyl-3-phenylisoquinolin-1(2H)-one(1609939-35-6)
• EPA Substance Registry System: 2-methoxy-8-methyl-3-phenylisoquinolin-1(2H)-one(1609939-35-6)

Safety Data

• Hazardous Substances Data: 1609939-35-6(Hazardous Substances Data)

Upstream product

• 57139-25-0 N-methoxy-2-methylbenzamide 
• 20187-61-5 mesyloxyacetophenone 

Relevant articles and documents

α-MsO/TsO/Cl ketones as oxidized alkyne equivalents: Redox-neutral rhodium(III)-catalyzed C-H activation for the synthesis of N-heterocycles

α-Halo and pseudohalo ketones are used for the first time as C(sp3)-based electrophiles in transition-metal-catalyzed C-H activation and as oxidized alkyne equivalents in RhIII-catalyzed redox-neutral annulations to generate diverse N-heterocycles. This transformation is efficient and scalable. Due to the mild reaction conditions, a variety of functional groups could be tolerated. Who needs alkynes? α-Halo and pseudohalo ketones (as C(sp3)-based electrophiles) are utilized as oxidized alkyne equivalents in RhIII-catalyzed redox-neutral annulations to efficiently generate diverse N-heterocycles. Owing to the mild reaction conditions, a variety of functional groups are tolerated.