18483-79-9

Basic information

• Product Name: Boranamine, 1,1-diethyl-
• Synonyms: Diethylboramin;Amino-diethyl-boran;Diethylaminoboran;Amino-diaethylboran;B.B-Diethyl-borazen;B-(Amino)-diethylboran
• CAS NO: 18483-79-9
• Molecular Formula: C4H12BN
• Molecular Weight: 84.957
• Mol File: 18483-79-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Boranamine, 1,1-diethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Boranamine, 1,1-diethyl-(18483-79-9)
• EPA Substance Registry System: Boranamine, 1,1-diethyl-(18483-79-9)

Safety Data

• Hazardous Substances Data: 18483-79-9(Hazardous Substances Data)

Upstream product

• 7397-53-7 bis(diethylboryl)amine 
• 108-18-9 diisopropylamine 
• 7664-41-7 ammonia 
• 4426-32-8 diethyl-thioborinic acid ethyl ester 

Relevant articles and documents

Reactivity of a Sterically Unencumbered α-Borylated Phosphorus Ylide towards Small Molecules

The influence of substituents on α-borylated phosphorus ylides (α-BCPs) has been investigated in a combined experimental and quantum chemical approach. The synthesis and characterization of Me3PC(H)B(iBu)2 (1), consisting of small Me substituents on phosphorous and iBu residues on boron, is reported. Compound 1 is accessible through a novel synthetic approach, which has been further elucidated through DFT studies. The reactivity of 1 towards various small molecules was probed and compared with that of a previously published derivative, Ph3PC(Me)BEt2 (2). Both α-BCPs react with NH3 to undergo heterolytic N?H bond cleavage. Different di- and trimeric ring structures were observed in the reaction products of 1 with CO and CO2. With PhNCO and PHNCS, the expected insertion products [Me3PC(H)(PhNCO)B(iBu)2] and [Me3PC(H)(PhNCS)B(iBu)2], respectively, were isolated.