22914-06-3

Basic information

• Product Name: Benzene, [1,1-bis(ethylthio)ethyl]-
• CAS NO: 22914-06-3
• Molecular Formula: C12H18S2
• Molecular Weight: 226.407
• Mol File: 22914-06-3.mol
• Article Data: 14

Chemical Properties

• CAS DataBase Reference: Benzene, [1,1-bis(ethylthio)ethyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [1,1-bis(ethylthio)ethyl]-(22914-06-3)
• EPA Substance Registry System: Benzene, [1,1-bis(ethylthio)ethyl]-(22914-06-3)

Safety Data

• Hazardous Substances Data: 22914-06-3(Hazardous Substances Data)

Upstream product

• 98-86-2 acetophenone 
• 75-08-1 ethanethiol 
• 70-11-1 α-bromoacetophenone 
• 4316-37-4 1,1,-diethoxy-1-phenylethane 
• 532-27-4 1-chloroacetophenone 
• 450-95-3 2-fluoroacetophenone 
• 7647-01-0 hydrogenchloride 
• 7334-52-3 benzaldehyde diethyldithioacetal 
• 74-88-4 methyl iodide 
• 614-21-1 2-nitroacetophenone 
• 40588-94-1 1,2-di(ethylthio)-1-phenylethene 
• 434-45-7 2,2,2-Trifluoroacetophenone 
• 4636-16-2 iodoacetophenone 
• 623-49-4 ethyl cyanoformate 

Downstream Products

• 100-41-4 ethylbenzene 
• 1084852-09-4 ethyl N-(2,6-dichlorophenyl)-2-(ethylthio)-2-phenylpropanimidothioate 
• 22906-18-9 ethyl α-methylbenzyl sulfide 
• 98-86-2 acetophenone 
• 75-08-1 ethanethiol 
• 22914-07-4 α-(ethylthio)styrene 

Relevant articles and documents

TITANIUM TETRACHLORIDE, AN EFFICIENT AND CONVENIENT REAGENT FOR THIOACETALIZATION

Aldehydes and ketones, when exposed to alkyl thiols or suitable alkane dithiols in presence of titanium tetrachloride, furnish near quantitative yields of the corresponding thioacetals.

Chemoselective (trans)thioacetalization of carbonyl compounds with a reusable lewis acid-surfactant-combined copper bis(dodecyl sulfate) catalyst in water

A Lewis acid-surfactant-combined copper bis(dodecyl sulfate) [Cu(DS) 2] catalyst served as an efficient and reusable catalyst for the thioacetalization and transthioacetalization of carbonyl compounds and O,O-acetals in water at room temperature. Some of the major advantages of this procedure are high chemoselectivity, ease of operation and purification without any organic solvent, and high yields. Georg Thieme Verlag Stuttgart.

Hafnium trifluoromethanesulfonate (hafnium triflate) as a highly efficient catalyst for chemoselective thioacetalization and transthioacetalization of carbonyl compounds

(Chemical Equation Presented) A range of carbonyl compounds including aliphatic and aromatic aldehydes and ketones were converted to the corresponding thioacetals in high yields in the presence of a catalytic amount of hafnium trifluoromethanesulfonate (0.1 mol %, room temperature). The mild conditions tolerated various sensitive functional and protecting groups and were racemization-free when applied to α-aminoaldehydes. Transacetalization and chemoselective thioacetalization of aromatic aldehydes in the presence of aliphatic aldehydes and ketones were also documented.