24566-13-0

Basic information

• Product Name: 2,6,10,14,18,22-Tetracosahexaene, 2,6,10,15,19,23-hexamethyl-, (E,E,E,Z)-
• CAS NO: 24566-13-0
• Molecular Formula: C30H50
• Molecular Weight: 410.727
• Mol File: 24566-13-0.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 2,6,10,14,18,22-Tetracosahexaene, 2,6,10,15,19,23-hexamethyl-, (E,E,E,Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2,6,10,14,18,22-Tetracosahexaene, 2,6,10,15,19,23-hexamethyl-, (E,E,E,Z)-(24566-13-0)
• EPA Substance Registry System: 2,6,10,14,18,22-Tetracosahexaene, 2,6,10,15,19,23-hexamethyl-, (E,E,E,Z)-(24566-13-0)

Safety Data

• Hazardous Substances Data: 24566-13-0(Hazardous Substances Data)

Upstream product

• 6784-45-8 (2E,6E)-farnesyl chloride 
• 106-28-5 Farnesol 
• 85611-33-2 (E)-3,7,11-trimethyldodeca-1,6,10-trien-3-yl acetate 
• 6784-45-8 1-chloro-3,7,11-trimethyldodeca-2,6,10-triene 
• 140184-23-2 ethyl ((2E,6E)-3,7,11-trimethyldodeca-2,6,10-trien-1-yl) carbonate 

Downstream Products

• 111-01-3 2,6,10,15,19,23-hexamethyltetracosane 

Relevant articles and documents

Ti/Pd bimetallic systems for the efficient allylation of carbonyl compounds and homocoupling reactions

The allylation, crotylation and prenylation of aldehydes and ketones with stable and easily handled allylic carbonates is promoted by a Ti/Pd catalytic system. This Ti/Pd bimetallic system is especially convenient for the allylation of ketones, which are infrequent substrates in other related protocols, and can be carried out intramolecularly to yield five- and six-membered cyclic products with good stereoselectivities. In addition, Ti/Pd-mediated reductions and Wuertz-type dimerisation reactions can be readily carried out from allyl carbonates and carboxylates.

PALLADIUM-CATALYZED REGIO- AND STEREOSELECTIVE DESULFONYLATION OF ALLYLIC SULFONES WITH LiHBEt3. APPLICATION TO THE SYNTHESIS OF SQUALENE

Allylic p-tolyl sulfones were easily desulfonylated to the corresponding alkenes by LiHBEt3 in the presence of a catalytic amount of under mild conditions with the preservation of the original stereochemistry.This reaction was successfully applied to the synthesis of squalene.