2973-86-6Relevant articles and documents
Efficient synthesis of carborane azo derivatives and their reactivity
Gao, Yang,Lin, Yue-Jian,Han, Ying-Feng,Jin, Guo-Xin
, p. 1585 - 1592 (2017)
An iridium(iii)-catalyzed C-N-bond-forming direct synthesis of carborane azo derivatives was developed. The reaction of o-carborane monocarboxylate with aryldiazonium salt in the presence of a catalytic amount of [Cp?IrCl2]2 and NaOA
Reductive lithiation of alkyl phenyl sulfides in diethyl ether. A ready access to α,α-dialkylbenzyllithiums
Screttas, Constantinos G.,Heropoulos, Georgios A.,Micha-Screttas, Maria,Steele, Barry R.,Catsoulacos, Dimitrios P.
, p. 5633 - 5635 (2007/10/03)
Diethyl ether is a convenient solvent for the conversion of benzylic phenyl sulfides to the corresponding organolithiums by an uncatalyzed reductive metalation, while catalysis by naphthalene is required to achieve the same reaction for alkyl phenyl sulfides. The addition of magnesium 2-ethoxyethoxide to solutions of unstable alkyllithiums prepared in this way provides storable reagents.
A method for the determination of the degree of association of organolithium compounds in liquid ammonia
Besten, Remco den,Harder, Sjoerd,Brandsma, Lambert
, p. 153 - 159 (2007/10/02)
A method for carrying out cryoscopy in liquid ammonia is presented.The degrees of association of some organolithium compounds in liquid ammonia have been determined.