30760-16-8

Basic information

• Product Name: 9-deoxo-9-iminoerythromycin A
• Synonyms: 9-deoxo-9-iminoerythromycin A
• CAS NO: 30760-16-8
• Molecular Weight: 732.953
• Mol File: 30760-16-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 9-deoxo-9-iminoerythromycin A(CAS DataBase Reference)
• NIST Chemistry Reference: 9-deoxo-9-iminoerythromycin A(30760-16-8)
• EPA Substance Registry System: 9-deoxo-9-iminoerythromycin A(30760-16-8)

Safety Data

• Hazardous Substances Data: 30760-16-8(Hazardous Substances Data)

Upstream product

• 882-33-7 diphenyldisulfane 
• 111321-02-9 erythromycin A 9-(E)-oxime 

Downstream Products

• 23893-13-2 anhydroerythromycin A 
• 114-07-8 erythromycin 
• 18423-89-7 L-cladinose 
• 130034-61-6 9-(benzylideneamino)-9-deoxo-12-deoxy-9,12-epoxyerythromycin A 
• 123943-98-6 9-N,11-O-benzylidene-9-deoxo-9-iminoerythromycin A 

Relevant articles and documents

From (E)- and (Z)-ketoximes to N-sulfenylimines, ketimines or ketones at will. Application to erythromycin derivatives

Reactions of (E)- and (Z)-ketoximes with trialkylphosphines and diphenyl disulfide (PhSSPh) have been compared to gain insight into the mechanisms involved and their potential applications. N-Sulfenylimine isomers and ketimines have been spectroscopically characterised. Both the E and Z isomers of erythromycin A oxime, when treated with Bu3P and PhSSPh (1:4:8 ratio), give the same N-phenylsulfenyl ketimine (of configuration E) as the major compound, whereas with Bu3P or Me3P and PySeSePy (1:8:4 ratio) afford the imine in good yield. Clarithromycin oxime behaves similarly.