61668-33-5

Basic information

• Product Name: Silane, [(2-bromo-1-phenylethenyl)oxy]trimethyl-
• CAS NO: 61668-33-5
• Molecular Formula: C11H15BrOSi
• Molecular Weight: 271.229
• Mol File: 61668-33-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Silane, [(2-bromo-1-phenylethenyl)oxy]trimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, [(2-bromo-1-phenylethenyl)oxy]trimethyl-(61668-33-5)
• EPA Substance Registry System: Silane, [(2-bromo-1-phenylethenyl)oxy]trimethyl-(61668-33-5)

Safety Data

• Hazardous Substances Data: 61668-33-5(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 70-11-1 α-bromoacetophenone 
• 13735-81-4 1-styrenyloxytrimethylsilane 

Downstream Products

• 61668-38-0 ((Z)-3-Trimethylsilanyl-1-trimethylsilanyloxy-propenyl)-benzene 
• 104464-28-0 Phosphoric acid diethyl ester (Z)-1-phenyl-2-trimethylsilanyl-vinyl ester 
• 64390-04-1 trans 1-(2-benzoylcyclopropyl)ethanone 
• 13735-78-9 1-phenyl-2-(trimethylsilyl)ethanone 
• 91873-57-3 bromo-2 phenyl-1 hexanedione-1,5 

Relevant articles and documents

Reaction des vinylogues d'hemiacetals avec les ethers d'enols β-heterosubstitues : nouvelle synthese et cyclisation de composes δ-dicarbonyles α-heterosubstitues

Reaction of hemiacetal vinylogs 1 in the presence of boron trifluoride etherate with silyl enol ethers 2 or 3 prepared from α-heterosubstituted ketones 7 or 9 yields α-halo δ-dicarbonyl compounds 4 (X = Cl, Br) or α-methoxy δ-dicarbonyl compounds 5.When s

α-Trialkylsilylketones from α-Bromoketones: Utilization of a 1,3-O to C Silyl Migration

A new route from α-bromoketones to α-trialkylsilylketones has been developed which demonstrates the viability of halogen-metal exchange vis-a-vis nucleophilic attack at silicon, even with the unhindered trimethylsilyl group.