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(-)-10-Camphorsulfonylimine

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Name

(-)-10-Camphorsulfonylimine

EINECS N/A
CAS No. 60886-80-8 Density 1.5 g/cm3
PSA 54.88000 LogP 2.11350
Solubility N/A Melting Point 228-230 °C(lit.)
Formula C10H15NO2S Boiling Point 337.2 °C at 760 mmHg
Molecular Weight 213.301 Flash Point 157.8 °C
Transport Information N/A Appearance White Cyrstalline Solid
Safety 26-36 Risk Codes 36/37/38
Molecular Structure Molecular Structure of 60886-80-8 ((1S)-(-)-CAMPHORSULFONYLIMINE) Hazard Symbols IrritantXi
Synonyms

(3aS,6R)-4,5,6,7-Tetrahydro-8,8-dimethyl-3H-3a,6-methano-2,1-benzisothiazole 2,2-dioxide;(3aS,6R)-8,8-Dimethyl-4,5,6,7-tetrahydro-3a,6-methano-2,1-benzothiazole 2,2-dioxide;3H-3a,6-Methano-2,1-benzisothiazole, 4,5,6,7-tetrahydro-8,8-dimethyl-, 2,2-dioxide, (3aS,6R)-;(1S)-(-)-Camphorsulfonylimine;

Article Data 22

(-)-10-Camphorsulfonylimine Specification

The (-)-10-Camphorsulfonylimine, with the CAS registry number 60886-80-8, is also known as 3H-3a,6-Methano-2,1-benzisothiazole, 4,5,6,7-tetrahydro-8,8-dimethyl-, 2,2-dioxide, (3aS,6R)-. It belongs to the product categories of Chiral Reagents; Bicyclic Monoterpenes; Biochemistry; Terpenes; Chiral Compound; Intermediates & Fine Chemicals; Pharmaceuticals. This chemical's molecular formula is C10H15NO2S and molecular weight is 213.30. What's more, its systematic name is (3aS,6R)-8,8-dimethyl-4,5,6,7-tetrahydro-3a,6-methano-2,1-benzothiazole 2,2-dioxide. It is a useful synthetic intermediate and is used for asymmetric hydroxylation. It should be sealed and stored in a cool and dry place. Moreover, it should be protected from oxides.

Physical properties of (-)-10-Camphorsulfonylimine are: (1)ACD/LogP: 0.02; (2)# of Rule of 5 Violations: 0; (3)#H bond acceptors: 3; (4)#H bond donors: 0; (5)#Freely Rotating Bonds: 0; (6)Polar Surface Area: 54.88 Å2; (7)Index of Refraction: 1.693; (8)Molar Refractivity: 54.48 cm3; (9)Molar Volume: 142 cm3; (10)Polarizability: 21.59×10-24cm3; (11)Surface Tension: 57.8 dyne/cm; (12)Density: 1.5 g/cm3; (13)Flash Point: 157.8 °C; (14)Enthalpy of Vaporization: 55.75 kJ/mol; (15)Boiling Point: 337.2 °C at 760 mmHg; (16)Vapour Pressure: 0.000208 mmHg at 25°C.

When you are using this chemical, please be cautious about it as the following:
It is irritating to eyes, respiratory system and skin. In case of contact with eyes, you should rinse immediately with plenty of water and seek medical advice. When using it, you need wear suitable protective clothing.

You can still convert the following datas into molecular structure:
(1)SMILES: O=S1(=O)/N=C3\[C@]2(C1)CC[C@@H](C2(C)C)C3
(2)Std. InChI: InChI=1S/C10H15NO2S/c1-9(2)7-3-4-10(9)6-14(12,13)11-8(10)5-7/h7H,3-6H2,1-2H3/t7-,10-/m1/s1
(3)Std. InChIKey: ZAHOEBNYVSWBBW-GMSGAONNSA-N

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