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Cas Database |
| Name |
(+)-Fenchol |
EINECS | 216-639-5 |
| CAS No. | 2217-02-9 | Density | 0.992g/cm3 |
| PSA | 20.23000 | LogP | 2.19350 |
| Solubility | Insoluble in water. | Melting Point |
39-45 ºC |
| Formula | C10H18 O | Boiling Point |
201-202 °C(lit.) |
| Molecular Weight | 154.252 | Flash Point | 165 ºF |
| Transport Information | N/A | Appearance | N/A |
| Safety | S22;S24/25 | Risk Codes | 36/38 |
| Molecular Structure |
|
Hazard Symbols | N/A |
| Synonyms |
Bicyclo[2.2.1]heptan-2-ol,1,3,3-trimethyl-, (1R-endo)-; (+)-Fenchol; (+)-Fenchyl alcohol; (+)-a-Fenchol; (+)-a-Fenchyl alcohol;(1R)-endo-(+)-Fenchol; (1R)-endo-(+)-Fenchyl alcohol; (1R-endo)-Fenchol;D-Fenchol; D-Fenchyl alcohol; a-(+)-Fenchol; a-Fenchol, (+)- |
Article Data | 48 |
(+)-Fenchol Synthetic route
A
- 2217-02-9
(1R)-endo-(+)-fenchol
| Conditions | Yield |
|---|---|
| Stage #1: (1R)-1,3,3-trimethyl-2-(2-methylprop-2-enyl)bicyclo[2.2.1]heptan-2-ol With oxygen; ozone In diethyl ether at -78℃; Oxidation; Stage #2: With lithium aluminium tetrahydride In diethyl ether at -78 - 20℃; Reduction; | A 0.18 g B 79% |
| Conditions | Yield |
|---|---|
| With lithium aluminium tetrahydride; diethyl ether | |
| With ethanol; sodium | |
| With ammonia; lithium; ammonium chloride In tetrahydrofuran at -75℃; for 0.916667h; Yield given; |
- 10467-10-4
ethylmagnesium iodide
- 7787-20-4
(1R)-fenchone
A
- 2217-02-9
(1R)-endo-(+)-fenchol
B
- 137255-07-3
(1R)-endo-2-ethylfenchol
| Conditions | Yield |
|---|---|
| In diethyl ether for 8h; Heating; | A 84 % Chromat. B 13 % Chromat. |
| Conditions | Yield |
|---|---|
| With aluminum oxide; sodium; isopropyl alcohol In tetrahydrofuran for 5h; Heating; | A 44.0 % Chromat. B 56.0 % Chromat. |
| With aluminum isopropoxide; isopropyl alcohol for 420h; Heating; | A 1.02 g B n/a |
| With tropinone reductase of Cochlearia officinalis; NADPH In methanol at 30℃; for 1h; pH=5; Kinetics; Reagent/catalyst; Enzymatic reaction; |
- 146203-05-6
(+)-8-bromo-α-fenchol
- 2217-02-9
(1R)-endo-(+)-fenchol
| Conditions | Yield |
|---|---|
| With lithium aluminium tetrahydride In diethyl ether for 6h; Ambient temperature; |
- 251319-23-0
1-[(1R,2R)-2-hydroxy-1,3,3-trimethylbicyclo[2.2.1]hept-2-yl]propan-2-one
A
- 2217-02-9
(1R)-endo-(+)-fenchol
| Conditions | Yield |
|---|---|
| With lithium aluminium tetrahydride Reduction; |
- 64-17-5
ethanol
- 7787-20-4
(1R)-fenchone
A
- 64439-31-2
(1R)-endo-(+)-fenchylalcohol
B
- 2217-02-9
(1R)-endo-(+)-fenchol
A
- 2217-02-9
(1R)-endo-(+)-fenchol
| Conditions | Yield |
|---|---|
| Stage #1: (1R)-2-ethenyl-1,3,3-trimethylbicyclo[2.2.1]heptan-2-ol With oxygen; ozone In diethyl ether at -78℃; Oxidation; Stage #2: With lithium aluminium tetrahydride In diethyl ether at -78 - 20℃; Reduction; | A 0.05 g B 0.07 g C n/a |
- 2217-02-9
(1R)-endo-(+)-fenchol
| Conditions | Yield |
|---|---|
| Multi-step reaction with 2 steps 1: O3/O2 / diethyl ether / -78 - 20 °C 2: LiAlH4 View Scheme | |
| Multi-step reaction with 2 steps 1.1: O3/O2 / diethyl ether / -78 °C 1.2: 8.28 g / Et3N / diethyl ether / -78 - 20 °C 2.1: LiAlH4 View Scheme |
- 18084-01-0, 21696-69-5, 131062-94-7, 137255-12-0, 137255-14-2
(1R,4S)-2-Ethynyl-1,3,3-trimethyl-bicyclo[2.2.1]heptan-2-ol
- 2217-02-9
(1R)-endo-(+)-fenchol
| Conditions | Yield |
|---|---|
| Multi-step reaction with 2 steps 1: 59 percent Chromat. / N-methylpyrrolidone, potassium hydroxide / 4 h / 20 °C 2: 84 percent Chromat. / diethyl ether / 8 h / Heating View Scheme |
(+)-Fenchol Chemical Properties
Chemical Name: (+)-Fenchol
IUPAC NAME: (1S,4R,6S)-1,5,5-Trimethylbicyclo[2.2.1]heptan-6-ol
CAS No.: 2217-02-9
EINECS: 216-639-5
Molecular Formula: C10H18O
Molecular Weight: 154.25 g/mol
Melting Point: 43-46 °C
Density: 0.992 g/cm3
Flash Point: 73.9 °C
Boiling Point: 202.9 °C at 760 mmHg
Following is the structure of Fenchol (CAS No.:2217-02-9):
Product Categories about Fenchol (CAS No.:2217-02-9) is refer to Miscellaneous
The chemical synonymous of Fenchol (CAS No.:2217-02-9) are (+)-Fenchol ; Fenchol ; Fenchyl alcohol ; Fema 2480 ; Alpha Fenchol ; (1r)-1,3,3-Trimethylbicyclo[2.2.1]heptan-2-Ol ; (1r)-(+)-Fenchyl alcohol ; (1r)-Endo-(+)-fenchol
(+)-Fenchol Safety Profile
Risk Statements about Fenchol (CAS No.:2217-02-9):
R36/38:Irritating to eyes and skin.
Safety Statements about Fenchol (CAS No.:2217-02-9):
S22:Do not breathe dust.
S24/25:Avoid contact with skin and eyes.
Attention:
1. Storage: Store in a cool, dry place. Keep container closed when not in use.
2. Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.
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