Basic Information | Post buying leads | Suppliers | Cas Database |
Conditions | Yield |
---|---|
With sodium hydroxide In ethanol; water for 4h; Reflux; | 99% |
With water; potassium hydroxide In methanol Reflux; | 93% |
With potassium hydroxide In methanol; water for 6h; Heating; | 81% |
Conditions | Yield |
---|---|
With sodium hydroxide; tetrabutylammomium bromide; water at 125℃; for 0.333333h; | 98% |
With cetyltrimethylammonim bromide; sodium hydroxide In water at 125℃; for 0.666667h; | 95% |
With tetrabutylammomium bromide; sodium hydroxide In water at 125℃; for 2h; Inert atmosphere; | 57% |
Conditions | Yield |
---|---|
With C46H49CoN3P4(2+)*2BF4(1-); hydrogen; potassium hydroxide In ethanol; acetonitrile at 60℃; under 22801.5 Torr; for 24h; Autoclave; Glovebox; chemoselective reaction; | 95% |
With sodium tetrahydroborate In methanol at 0 - 25℃; for 2h; Inert atmosphere; | 92% |
With diethyl 2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate; tris[3,5-bis(trifluoromethyl)phenyl]-borane In 1,4-dioxane at 25℃; for 12h; Glovebox; | 66% |
(4-ethynylphenyl)methanol
(4-vinyl-phenyl)-methanol
Conditions | Yield |
---|---|
With hydrogen In acetonitrile at 110℃; under 7500.75 Torr; for 15h; chemoselective reaction; | 94% |
With bis-triphenylphosphine-palladium(II) chloride; tri-n-butyl-tin hydride In tetrahydrofuran at 20℃; Inert atmosphere; |
Conditions | Yield |
---|---|
With lithium aluminium tetrahydride In tetrahydrofuran for 0.166667h; Inert atmosphere; Cooling with ice; | 91% |
Conditions | Yield |
---|---|
With caesium carbonate; triphenylphosphine; palladium dichloride In tetrahydrofuran; water at 85℃; for 22h; Suzuki-Miyaura reaction; | 82% |
4-Vinylbenzyl chloride
A
(4-vinyl-phenyl)-methanol
B
di(4-vinylbenzyl)ether
Conditions | Yield |
---|---|
With sodium hydroxide; water In ethanol at 20℃; for 24h; | A 19% B 81% |
(4-vinyl-phenyl)-methanol
Conditions | Yield |
---|---|
With methanol at 20℃; for 0.5h; Inert atmosphere; | 80% |
Conditions | Yield |
---|---|
With palladium diacetate; tetra-(n-butyl)ammonium iodide; triethylamine; CyJohnPhos In N,N-dimethyl-formamide; toluene at 120℃; under 11251.1 Torr; for 0.333333h; Mizoroki-Heck coupling; | 78% |
With palladium diacetate; tetra-(n-butyl)ammonium iodide; triethylamine; johnphos In N,N-dimethyl-formamide; toluene at 120℃; under 11251.1 Torr; for 0.333333h; Heck Reaction; | 78% |
Conditions | Yield |
---|---|
With phenylsilane; C34H30CoO6; potassium In tetrahydrofuran at 20℃; for 20h; Inert atmosphere; Schlenk technique; Glovebox; | 64% |
With lithium aluminium tetrahydride In tetrahydrofuran; diethyl ether at 0 - 20℃; | 62% |
With lithium aluminium tetrahydride In tetrahydrofuran; diethyl ether at 0 - 20℃; for 1h; | 62% |
With lithium aluminium tetrahydride In tetrahydrofuran; diethyl ether at 0 - 20℃; for 1h; | 62% |
With lithium aluminium tetrahydride In tetrahydrofuran; diethyl ether at 0 - 25℃; for 1h; Inert atmosphere; | 423 mg |
The (4-Vinylphenyl)methanol, with the CAS registry number 1074-61-9, has the systematic name of (4-ethenylphenyl)methanol. It belongs to the product category of API intermediate. And the molecular formula of this chemical is C9H10O.
The physical properties of (4-Vinylphenyl)methanol are as following: (1)ACD/LogP: 1.52; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 1.52; (4)ACD/LogD (pH 7.4): 1.52; (5)ACD/BCF (pH 5.5): 8.36; (6)ACD/BCF (pH 7.4): 8.36; (7)ACD/KOC (pH 5.5): 159.11; (8)ACD/KOC (pH 7.4): 159.11; (9)#H bond acceptors: 1; (10)#H bond donors: 1; (11)#Freely Rotating Bonds: 3; (12)Polar Surface Area: 20.23 Å2; (13)Index of Refraction: 1.59; (14)Molar Refractivity: 43.62 cm3; (15)Molar Volume: 129.1 cm3; (16)Polarizability: 17.29×10-24cm3; (17)Surface Tension: 40.4 dyne/cm; (18)Density: 1.038 g/cm3; (19)Flash Point: 115.4 °C; (20)Enthalpy of Vaporization: 51.17 kJ/mol; (21)Boiling Point: 247.1 °C at 760 mmHg; (22)Vapour Pressure: 0.0139 mmHg at 25°C.
You can still convert the following datas into molecular structure:
(1)SMILES: OCc1ccc(C=C)cc1
(2)InChI: InChI=1/C9H10O/c1-2-8-3-5-9(7-10)6-4-8/h2-6,10H,1,7H2
(3)InChIKey: CLECMSNCZUMKLM-UHFFFAOYAH