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(R)-(-)-2-Chloropropan-1-ol
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Name

(R)-(-)-2-Chloropropan-1-ol

 EINECS N/A
CAS No. 37493-14-4 Density 1.082 g/cm3
PSA 20.23000 LogP 0.60600
Solubility soluble Melting Point N/A
Formula C3H7ClO Boiling Point 133.5 °C at 760 mmHg
Molecular Weight 94.541 Flash Point 44.4 °C
Transport Information UN 2611 Appearance clear colourless liquid
Safety 36/37/39-27-26-16 Risk Codes 36/37/38-20/21/22-10
Molecular Structure Molecular Structure of 37493-14-4 ((R)-(-)-2-Chloropropan-1-ol) Hazard Symbols HarmfulXn
Synonyms

1-Propanol,2-chloro-, (R)-;(-)-(R)-2-Chloropropanol;(R)-(-)-2-Chloro-1-propanol;(R)-2-Chloro-1-propanol;

Article Data 9

(R)-(-)-2-Chloropropan-1-ol Synthetic route

42411-39-2

(R)-ethyl 2-chloropropanoate

37493-14-4

(R)-(-)-2-chloro-propan-1-ol

Conditions
ConditionsYield
With lithium aluminium tetrahydride In diethyl ether for 2h;78%
With lithium aluminium tetrahydride In diethyl ether 1.) 0 deg C, 2.5 h; 2.) up to r.t. 15 h;35%
With lithium aluminium tetrahydride In diethyl ether
With lithium aluminium tetrahydride In diethyl ether at 0℃; Heating;
687-47-8

(S)-Ethyl lactate

37493-14-4

(R)-(-)-2-chloro-propan-1-ol

Conditions
ConditionsYield
(i) PCl3, (ii) LiAlH4; Multistep reaction;
7474-05-7

(R)-2-chloropropionic acid

37493-14-4

(R)-(-)-2-chloro-propan-1-ol

Conditions
ConditionsYield
With lithium aluminium tetrahydride In diethyl ether
187737-37-7

propene

A

19210-21-0

(S)-2-chloropropan-1-ol

B

37493-16-6

1-chloro-2(S)-hydroxypropane

C

19141-39-0

(R)-(-)-1-chloro-2-propanol

D

37493-14-4

(R)-(-)-2-chloro-propan-1-ol

Conditions
ConditionsYield
With copper dichloride; [Pd(CH3CN)2{(S)-BINAP}](BF4)2; 1,3-diacetyl acetone In tetrahydrofuran at 25℃; Product distribution; Further Variations:; Catalysts; Solvents; Reagents;
692291-15-9

2-chloropropanal

37493-14-4

(R)-(-)-2-chloro-propan-1-ol

Conditions
ConditionsYield
With sodium tetrahydroborate In methanol

3-(2-Chloro-4-hydroxy-phenyl)-[1,4]oxazepane-4-carboxylic acid tert-butyl ester

37493-14-4

(R)-(-)-2-chloro-propan-1-ol

3-[2-Chloro-4-((R)-2-hydroxy-1-methyl-ethoxy)-phenyl]-[1,4]oxazepane-4-carboxylic acid tert-butyl ester

Conditions
ConditionsYield
With potassium hydroxide In N,N-dimethyl-formamide at 100℃;93%
98-59-9

p-toluenesulfonyl chloride

37493-14-4

(R)-(-)-2-chloro-propan-1-ol

113787-72-7

(R)-2-chloropropyl p-toluenesulfonate

Conditions
ConditionsYield
With pyridine 1.) 0 deg C, 1.5 h; 2.) up to r.t. 15 h;78%
37493-14-4

(R)-(-)-2-chloro-propan-1-ol

57045-26-8

4-Ethoxycarbonyloxybenzoyl chloride

189076-28-6

(R)-(2-Chloropropyl)-4-ethoxycarbonyloxybenzoate

Conditions
ConditionsYield
With potassium carbonate In diethyl ether for 5h; Heating;72.7%
619-89-6

p-nitrocinnamic acid

37493-14-4

(R)-(-)-2-chloro-propan-1-ol

p-Aminozimtsaeure-R(-)-2-chlorpropylester

Conditions
ConditionsYield
(i) SOCl2, (ii) /BRN= 6312547/, (iii) FeCl2, NH3; Multistep reaction;
358-23-6

trifluoromethylsulfonic anhydride

37493-14-4

(R)-(-)-2-chloro-propan-1-ol

120723-94-6

(2R)-1-trifluoromethanesulfonyloxy-2-chloropropane

Conditions
ConditionsYield
With pyridine In dichloromethane at -60℃;
With pyridine In dichloromethane at -50℃; for 0.5h;11.7 g

(R)-(-)-2-Chloropropan-1-ol Specification

The (R)-(-)-2-Chloropropan-1-ol with the CAS number 37493-14-4 is also called 1-Propanol, 2-chloro-,(2R)- (9CI). Both the systematic name and IUPAC name are (2R)-2-chloropropan-1-ol. Its molecular formula is C3H7ClO. This chemical belongs to the following product categories: (1)Chiral; (2)API intermediates.

The properties of the (R)-(-)-2-Chloropropan-1-ol are: (1)ACD/LogP: 0.27; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 0.27; (4)ACD/LogD (pH 7.4): 0.27; (5)ACD/BCF (pH 5.5): 1; (6)ACD/BCF (pH 7.4): 1; (7)ACD/KOC (pH 5.5): 33.34; (8)ACD/KOC (pH 7.4): 33.34; (9)#H bond acceptors: 1; (10)#H bond donors: 1; (11)#Freely Rotating Bonds: 2; (12)Polar Surface Area: 9.23 Å2; (13)Index of Refraction: 1.424; (14)Molar Refractivity: 22.29 cm3; (15)Molar Volume: 87.3 cm3; (16)Polarizability: 8.83×10-24cm3; (17)Surface Tension: 29.8 dyne/cm; (18)Enthalpy of Vaporization: 43.23 kJ/mol; (19)Vapour Pressure: 3.68 mmHg at 25°C.

While using this chemical, you should be very cautious. This chemical is flammable and harmful by inhalation, in contact with skin and if swallowed. It is not only irritating to skin, but also irritating to eyes and respiratory system. Therefore, you should take the following instructions. Firstly, you should wear suitable protective clothing, gloves and eye/face protection. Secondly in case of contact with eyes, you should rinse immediately with plenty of water and seek medical advice. Thirdly you should keep this chemical away from sources of ignition. Finally you should take off immediately all contaminated clothing.

You can still convert the following datas into molecular structure:
(1)SMILES: Cl[C@H](C)CO
(2)InChI: InChI=1/C3H7ClO/c1-3(4)2-5/h3,5H,2H2,1H3/t3-/m1/s1
(3)InChIKey: VZIQXGLTRZLBEX-GSVOUGTGBS

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