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Cas Database |
| Name |
1,1,1,3-Tetrachloro-propane |
EINECS | 213-981-7 |
| CAS No. | 1070-78-6 | Density | 1.471 g/cm3 |
| PSA | 0.00000 | LogP | 2.98550 |
| Solubility | N/A | Melting Point |
-35 °C |
| Formula | C3H4Cl4 | Boiling Point | 161.259 °C at 760 mmHg |
| Molecular Weight | 181.877 | Flash Point | 51.41 °C |
| Transport Information | N/A | Appearance | Colorless |
| Safety | Risk Codes | N/A | |
| Molecular Structure |
|
Hazard Symbols |
 Xi
|
| Synonyms |
1,1,1,3-Tetrachloropropane;HCC 250fb; |
Article Data | 69 |
1,1,1,3-Tetrachloro-propane Synthetic route
| Conditions | Yield |
|---|---|
| With iron; trimethyl orthoformate at 100℃; under 1500.15 Torr; for 1h; | 98.1% |
| With iron(III) chloride; phosphoric acid tributyl ester; iron at 110℃; under 5931.67 Torr; Reagent/catalyst; Pressure; Flow reactor; Large scale; | 96% |
| iron(III) chloride; triethyl phosphate; iron at 110 - 134℃; under 1875.19 - 6000.6 Torr; Autoclave; Inert atmosphere; | 91% |
| Conditions | Yield |
|---|---|
| With benzene; dibenzoyl peroxide at 70℃; under 20594.2 Torr; |
| Conditions | Yield |
|---|---|
| beim Chlorieren; zunaechst im Sonnenlicht in der Dampfphase, dann in fluessiger Phase unter Kuehlung; |
- 56-23-5
tetrachloromethane
- 74-85-1
ethene
A
- 2467-10-9
1,1,1,5-tetrachloropentane
B
- 2677-33-0
1,1,5-trichloro-pent-1-ene
C
- 1070-78-6
1,1,1,3-tetrachloropropane
D
- 13275-19-9
1,1,1,3-tetrachlorobutane
| Conditions | Yield |
|---|---|
| With diethyl amine hydrochloride; 2-hydroxy-2-phenylacetophenone; iron(III) chloride In isopropyl alcohol Further byproducts given; |
- 56-23-5
tetrachloromethane
- 74-85-1
ethene
A
- 2467-10-9
1,1,1,5-tetrachloropentane
B
- 2677-33-0
1,1,5-trichloro-pent-1-ene
C
- 1070-78-6
1,1,1,3-tetrachloropropane
D
- 34909-84-7
1,3,5-trichloro-2-pentene
| Conditions | Yield |
|---|---|
| With diethyl amine hydrochloride; 2-hydroxy-2-phenylacetophenone In isopropyl alcohol Further byproducts given; |
- 56-23-5
tetrachloromethane
- 74-85-1
ethene
A
- 2467-10-9
1,1,1,5-tetrachloropentane
B
- 1070-78-6
1,1,1,3-tetrachloropropane
C
- 13275-19-9
1,1,1,3-tetrachlorobutane
D
- 24616-07-7
1,3,3,5-tetrachloropentane
| Conditions | Yield |
|---|---|
| With 2-hydroxy-2-phenylacetophenone; diethylamine; iron(III) chloride In isopropyl alcohol Further byproducts given; |
- 56-23-5
tetrachloromethane
- 74-85-1
ethene
A
- 2467-10-9
1,1,1,5-tetrachloropentane
B
- 1070-78-6
1,1,1,3-tetrachloropropane
C
- 24616-07-7
1,3,3,5-tetrachloropentane
D
- 34909-84-7
1,3,5-trichloro-2-pentene
| Conditions | Yield |
|---|---|
| With diethyl amine hydrochloride; 2-hydroxy-2-phenylacetophenone; iron(III) chloride Further byproducts given; |
- 56-23-5
tetrachloromethane
- 187737-37-7
propene
- 74-85-1
ethene
A
- 2467-10-9
1,1,1,5-tetrachloropentane
B
- 13275-22-4
1,1,1,5-tetrachloro-3-methylhexane
C
- 1070-78-6
1,1,1,3-tetrachloropropane
D
- 13275-19-9
1,1,1,3-tetrachlorobutane
E
- 3922-36-9
1,1,1,7-tetrachloroheptane
F
- 17977-23-0, 29293-15-0, 29293-20-7, 29293-21-8, 29293-22-9, 31031-26-2
1,1,1,7-tetrachloro-3,5-dimethyl-octane
| Conditions | Yield |
|---|---|
| With dibenzoyl peroxide at 90℃; for 3h; Product distribution; variation of the reactant ratio; |
- 56-23-5
tetrachloromethane
- 74-85-1
ethene
A
- 2467-10-9
1,1,1,5-tetrachloropentane
B
- 1070-78-6
1,1,1,3-tetrachloropropane
| Conditions | Yield |
|---|---|
| FeIIFe2IIICl8(CH3CN)6 In N,N-dimethyl acetamide; acetonitrile at 130℃; under 15200 Torr; for 4h; Product distribution; Mechanism; other concentrations of CH3CN, DMA; other catalyst; | A 1.6 % Turnov. B 98.4 % Turnov. |
| FeIIFe2IIICl8(CH3CN)6 In N,N-dimethyl acetamide; acetonitrile at 130℃; under 15200 Torr; for 4h; | A 1.6 % Turnov. B 98.4 % Turnov. |
- 56-23-5
tetrachloromethane
- 74-85-1
ethene
A
- 2467-10-9
1,1,1,5-tetrachloropentane
B
- 1070-78-6
1,1,1,3-tetrachloropropane
C
- 3922-36-9
1,1,1,7-tetrachloroheptane
D
- 1561-48-4
1,1,1,9-tetrachloro-nonane
E
- 3922-34-7
1,1,1,11-tetrachloro-undecane
| Conditions | Yield |
|---|---|
| With chromium(0) hexacarbonyl at 120℃; Product distribution; relative rate of telomerization initiated by Cr(CO)6 and further initiator; partial chain-transfer constants; |
1,1,1,3-Tetrachloro-propane Chemical Properties
IUPAC Name: 1,1,1,3-Tetrachloro-propane
The MF of 1,1,1,3-Tetrachloro-propane (CAS NO.1070-78-6) is C3H4Cl4.
The MW of 1,1,1,3-Tetrachloro-propane (CAS NO.1070-78-6) is 181.88.
Synonyms of 1,1,1,3-Tetrachloro-propane (CAS NO.1070-78-6): 1,1,1,3-Tetrachloro-propan ; Propane,1,1,1,3-tetrachloro- ; Tetrachloropropane
Index of Refraction: 1.482
EINECS: 213-981-7
Density: 1.471 g/ml
Flash Point: 51.4 °C
Boiling Point: 161.3 °C
Melting Point: -35 °C
1,1,1,3-Tetrachloro-propane Uses
1,1,1,3-Tetrachloro-propane (CAS NO.1070-78-6) is used for the preparation of three allyl chloride, trifluoro-propylene, also as solvent.
1,1,1,3-Tetrachloro-propane Toxicity Data With Reference
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| mouse | LDLo | oral | 1mL/kg (1mL/kg) | National Technical Information Service. Vol. OTS0520626, | |
| rabbit | LD50 | skin | > 2mL/kg (2mL/kg) | National Technical Information Service. Vol. OTS0520626, | |
| rat | LCLo | inhalation | 4700ppm/6H (4700ppm) | BEHAVIORAL: ATAXIA | National Technical Information Service. Vol. OTS0520625, |
| rat | LD50 | oral | 490mg/kg (490mg/kg) | Office of Toxic Substances Report. Vol. OTS0515505, |
1,1,1,3-Tetrachloro-propane Consensus Reports
Reported in EPA TSCA Inventory.
1,1,1,3-Tetrachloro-propane Safety Profile
Moderately toxic by ingestion. When heated to decomposition it emits toxic fumes of Cl−. See also CHLORINATED HYDROCARBONS, ALIPHATIC.Safety information of 1,1,1,3-Tetrachloro-propane (CAS NO.1070-78-6):
Hazard Codes 
Xi
RTECS TZ7000000
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