Basic Information | Post buying leads | Suppliers | Cas Database |
Name |
1,4-Benzenediamine,2,3,5,6-tetramethyl- |
EINECS | 221-457-4 |
CAS No. | 3102-87-2 | Density | 1.032 g/cm3 |
PSA | 52.04000 | LogP | 3.24700 |
Solubility | N/A | Melting Point |
150-155 °C(lit.) |
Formula | C10H16N2 | Boiling Point | 310.6 °C at 760 mmHg |
Molecular Weight | 164.25 | Flash Point | 167.8 °C |
Transport Information | N/A | Appearance | beige fine crystalline powder |
Safety | 26-36-22 | Risk Codes | 36/37/38-40 |
Molecular Structure | Hazard Symbols | Xi,Xn | |
Synonyms |
p-Phenylenediamine,2,3,5,6-tetramethyl- (6CI,7CI,8CI);1,4-Diamino-2,3,5,6-tetramethylbenzene;2,3,5,6-Tetramethyl-1,4-benzenediamine;2,3,5,6-Tetramethyl-1,4-phenylenediamine;2,3,5,6-Tetramethyl-p-phenylenediamine;2,3,5,6-Tetramethylphenylenediamine;DAD(H);Diaminodurene;Diaminodurol;Durenediamine;NSC 158251; |
Article Data | 9 |
Conditions | Yield |
---|---|
With ethanol; nickel at 60℃; Hydrogenation; | |
With ethanol; nickel under 110326 Torr; Hydrogenation; | |
With nickel; hydrazine hydrate In ethanol at 60 - 70℃; |
2,3,5,6-tetramethyl-4-amino-1-nitrobenzene
tetramethyl-p-phenylenediamine
Conditions | Yield |
---|---|
With ammonium sulfide at 135℃; |
tetramethyl-p-phenylenediamine
Conditions | Yield |
---|---|
With acetic acid; zinc |
A
tetramethyl-p-phenylenediamine
B
2,3,5,6-tetramethyl-4-amino-1-nitrobenzene
Conditions | Yield |
---|---|
With ammonium sulfide at 130℃; |
Conditions | Yield |
---|---|
With disodium telluride In 1,4-dioxane; water at 50℃; for 7h; twice amount of reducing agent; Yield given; |
tetramethyl-p-phenylenediamine
1,4,5,8-naphthalenetetracarboxylic dianhydride
2,7-diaminobenzo[lmn][3,8]phenanthroline-1,3,6,8(2H,7H)-tetraone
Conditions | Yield |
---|---|
With NH-pyrazole at 110℃; for 17h; | 95% |
tetramethyl-p-phenylenediamine
perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride
2,9-bis-(4-amino-2,3,5,6-tetramethylphenyl)anthra[2,1,9-def;6,5,10-d′e′f ′]diisoquinolin-1,3,8,10-tetraone
Conditions | Yield |
---|---|
With NH-pyrazole at 140℃; for 4h; | 95% |
Conditions | Yield |
---|---|
With pyridine at 0 - 20℃; for 1h; | 95% |
Conditions | Yield |
---|---|
Stage #1: tetramethyl-p-phenylenediamine With n-butyllithium In tetrahydrofuran; hexane at 20℃; for 16h; Stage #2: chloro-trimethyl-silane In tetrahydrofuran; hexane at 20℃; for 12h; | 91% |
dichloromethane
trans,mer-[Ti(t-butylimide)Cl2(pyridine)3]
tetramethyl-p-phenylenediamine
Conditions | Yield |
---|---|
In dichloromethane byproducts: tBuNH2; (Ar); for 2 h at room temp.; evapd., layered with hexane at room temp. from CH2Cl2 soln.; | 91% |
The CAS register number of 1,4-Benzenediamine,2,3,5,6-tetramethyl- is 3102-87-2. It also can be called as Diaminodurene and the IUPAC name about this chemical is 2,3,5,6-tetramethylbenzene-1,4-diamine. The molecular formula about this chemical is C10H16N2 and the molecular weight is 164.25. It belongs to the following product categories which include Fluorenes, etc. (reagent for high-performance polymer research); Functional Materials; Reagent for High-Performance Polymer Research and so on.
Physical properties about 1,4-Benzenediamine,2,3,5,6-tetramethyl- are: (1)ACD/LogP: 1.16; (2)ACD/LogD (pH 5.5): 0.45; (3)ACD/LogD (pH 7.4): 1.13; (4)ACD/BCF (pH 5.5): 1; (5)ACD/BCF (pH 7.4): 4.24; (6)ACD/KOC (pH 5.5): 20.08; (7)ACD/KOC (pH 7.4): 96.46; (8)#H bond acceptors: 2; (9)#H bond donors: 4; (10)#Freely Rotating Bonds: 2; (11)Polar Surface Area: 6.48Å2; (12)Index of Refraction: 1.594; (13)Molar Refractivity: 54.02 cm3; (14)Molar Volume: 159 cm3; (15)Polarizability: 21.41x10-24cm3; (16)Surface Tension: 43.9 dyne/cm; (17)Enthalpy of Vaporization: 55.14 kJ/mol; (18)Boiling Point: 310.6 °C at 760 mmHg; (19)Vapour Pressure: 0.000595 mmHg at 25°C.
Uses of 1,4-Benzenediamine,2,3,5,6-tetramethyl-: it can be used to produce 1,4-bis-(2,5-dimethylpyrrol-1-yl)-2,3,5,6-tetramethylbenzene with hexane-2,5-dione at heating. This reaction will need reagent conc. HCl and solvent ethanol with reaction time of 1 hours. The yield is about 62%.
When you are using this chemical, please be cautious about it as the following:
This chemical is irritating to eyes, respiratory system and skin. It is limited evidence of a carcinogenic effect. When you are using it, please wear suitable protective clothing and do not breathe dust. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
You can still convert the following datas into molecular structure:
(1)SMILES: Nc1c(c(c(c(c1C)C)N)C)C
(2)InChI: InChI=1/C10H16N2/c1-5-6(2)10(12)8(4)7(3)9(5)11/h11-12H2,1-4H3
(3)InChIKey: WCZNKVPCIFMXEQ-UHFFFAOYAX
(4)Std. InChI: InChI=1S/C10H16N2/c1-5-6(2)10(12)8(4)7(3)9(5)11/h11-12H2,1-4H3
(5)Std. InChIKey: WCZNKVPCIFMXEQ-UHFFFAOYSA-N