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| Name |
1-Bromo-4-chloro-2-fluorobenzene |
EINECS | N/A |
| CAS No. | 1996-29-8 | Density | 1.719 g/cm3 |
| PSA | 0.00000 | LogP | 3.24160 |
| Solubility | insoluble in water | Melting Point |
N/A |
| Formula | C6H3BrClF | Boiling Point | 187.3 °C at 760 mmHg |
| Molecular Weight | 209.445 | Flash Point | 67.1 °C |
| Transport Information | N/A | Appearance | CLEAR COLORLESS TO PALE YELLOW LIQUID |
| Safety | 37/39-26 | Risk Codes | 36/37/38 |
| Molecular Structure |
|
Hazard Symbols |
 Xi
|
| Synonyms |
4-Bromo-1-chloro-3-fluorobenzene; |
1-Bromo-4-chloro-2-fluorobenzene Synthetic route
- 1996-29-8
1-bromo-4-chloro-2-fluorobenzene
Conditions
| Conditions | Yield |
|---|---|
| (i) NaNO2, aq. HCl, (ii) HBF4, (iii) (thermolysis); Multistep reaction; |
- 57946-56-2
2-fluoro-4-chloroaniline
- 1996-29-8
1-bromo-4-chloro-2-fluorobenzene
Conditions
| Conditions | Yield |
|---|---|
| Stage #1: 2-fluoro-4-chloroaniline With hydrogen bromide; sodium nitrite In water at -10℃; for 0.5h; Stage #2: With hydrogen bromide; copper(I) bromide In water at -10 - 55℃; for 0.333333h; |
Conditions
| Conditions | Yield |
|---|---|
| With sodium bromide; copper(I) bromide; sodium sulfite; sodium nitrite In hydrogen bromide |
Conditions
| Conditions | Yield |
|---|---|
| With 18-crown-6 ether In dimethyl sulfoxide for 1h; Reflux; | 99% |
| With sodium t-butanolate In N,N-dimethyl acetamide for 18h; Inert atmosphere; Heating; | 90% |
| With 18-crown-6 ether; potassium fluoride on basic alumina In dimethyl sulfoxide for 8h; Inert atmosphere; Reflux; | 83% |
- 542-85-8
Ethyl isothiocyanate
- 1996-29-8
1-bromo-4-chloro-2-fluorobenzene
- 1269242-19-4
4-chloro-N-ethyl-2-fluorobenzenecarbothioamide
Conditions
| Conditions | Yield |
|---|---|
| Stage #1: 1-bromo-4-chloro-2-fluorobenzene With n-butyllithium In tetrahydrofuran at -78℃; Stage #2: Ethyl isothiocyanate In diethyl ether at -78℃; | 97% |
- 201230-82-2
carbon monoxide
- 1996-29-8
1-bromo-4-chloro-2-fluorobenzene
- 1670-14-0
benzamidine monohydrochloride
- 7012-94-4
7-chloro-5-methyl-2-phenylquinazolin-4(3H)-one
Conditions
| Conditions | Yield |
|---|---|
| With palladium diacetate; N-ethyl-N,N-diisopropylamine; catacxium A In N,N-dimethyl acetamide at 140℃; under 7500.75 Torr; for 22h; Inert atmosphere; Autoclave; | 97% |
- 36016-38-3
tert-Butyl N-hydroxycarbamate
- 1996-29-8
1-bromo-4-chloro-2-fluorobenzene
- 1160491-84-8
t-butyl N-(5-bromo-2-chlorophenoxy) carbamate
Conditions
| Conditions | Yield |
|---|---|
| With potassium hydroxide In dimethyl sulfoxide at 60℃; for 2h; | 96% |
- 1996-29-8
1-bromo-4-chloro-2-fluorobenzene
- 922552-53-2
(2-bromo-5-chlorophenyl)hydrazine
Conditions
| Conditions | Yield |
|---|---|
| With hydrazine hydrate In dimethyl sulfoxide at 70℃; for 72h; | 96% |
Conditions
| Conditions | Yield |
|---|---|
| With potassium phosphate In N,N-dimethyl-formamide at 150℃; | 93% |
- 1996-29-8
1-bromo-4-chloro-2-fluorobenzene
- 622-78-6
Benzyl isothiocyanate
- 1269242-21-8
4-chloro-2-fluoro-N-(phenylmethyl)benzenecarbothioamide
Conditions
| Conditions | Yield |
|---|---|
| Stage #1: 1-bromo-4-chloro-2-fluorobenzene With n-butyllithium In tetrahydrofuran at -78℃; Stage #2: Benzyl isothiocyanate In diethyl ether at -78℃; | 92% |
1-Bromo-4-chloro-2-fluorobenzene Chemical Properties
IUPAC Name: 1-bromo-4-chloro-2-fluorobenzene
The MF of 1-Bromo-4-chloro-2-fluorobenzene(1996-29-8): C6H3BrClF
The MW of 1-Bromo-4-chloro-2-fluorobenzene(1996-29-8): 209.44
bp: 91-92 °C at 20 mm Hg(lit.)
density: 1.678 g/mL at 25 °C(lit.)
refractive index: n20/D 1.556(lit.)
Fp: 198 °F
Water Solubility: INSOLUBLE
Categories: Aromatic Halides (substituted);Bromine Compounds;Chlorine Compounds;Fluorine Compounds;Aryl;C6;Halogenated Hydrocarbons
Synonyms: 2-BROMO-5-CHLORO-1-FLUOROBENZENE;2-BROMO-5-CHLOROFLUOROBENZENE;2-FLUORO-4-CHLOROBROMOBENZENE;1-BROMO-4-CHLORO-2-FLUOROBENZENE;1-Bromo-4-chloro-2-fluorobenzene 97%;4-CHLORO-2-FLUORO BROMOBENZENE;1-Bromo-4-chloro-2-fluorobenzene97%
The Structure of 1-Bromo-4-chloro-2-fluorobenzene(1996-29-8):
The MF of 1-Bromo-4-chloro-2-fluorobenzene(1996-29-8): C6H3BrClF
The MW of 1-Bromo-4-chloro-2-fluorobenzene(1996-29-8): 209.44
bp: 91-92 °C at 20 mm Hg(lit.)
density: 1.678 g/mL at 25 °C(lit.)
refractive index: n20/D 1.556(lit.)
Fp: 198 °F
Water Solubility: INSOLUBLE
Categories: Aromatic Halides (substituted);Bromine Compounds;Chlorine Compounds;Fluorine Compounds;Aryl;C6;Halogenated Hydrocarbons
Synonyms: 2-BROMO-5-CHLORO-1-FLUOROBENZENE;2-BROMO-5-CHLOROFLUOROBENZENE;2-FLUORO-4-CHLOROBROMOBENZENE;1-BROMO-4-CHLORO-2-FLUOROBENZENE;1-Bromo-4-chloro-2-fluorobenzene 97%;4-CHLORO-2-FLUORO BROMOBENZENE;1-Bromo-4-chloro-2-fluorobenzene97%
The Structure of 1-Bromo-4-chloro-2-fluorobenzene(1996-29-8):
1-Bromo-4-chloro-2-fluorobenzene Safety Profile
Hazard Codes: 
Xi
Risk Statements: 36/37/38
36/37/38: Irritating to eyes, respiratory system and skin
Safety Statements: 37/39-26
37/39: Wear suitable gloves and eye/face protection
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
WGK Germany: 3
Hazard Note: Irritant
Xi Risk Statements: 36/37/38
36/37/38: Irritating to eyes, respiratory system and skin
Safety Statements: 37/39-26
37/39: Wear suitable gloves and eye/face protection
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
WGK Germany: 3
Hazard Note: Irritant
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1-Bromo-4-chloro-2-fluorobenzene
