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2-Ethoxyethyl methacrylate

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Name

2-Ethoxyethyl methacrylate

EINECS 219-135-3
CAS No. 2370-63-0 Density 0.957 g/cm3
PSA 35.53000 LogP 1.14220
Solubility 17.05g/L at 20℃ Melting Point <25 °C
Formula C8H14O3 Boiling Point 182.408 °C at 760 mmHg
Molecular Weight 158.197 Flash Point 71.667 °C
Transport Information N/A Appearance N/A
Safety 26-27-36/37/39 Risk Codes 36/37/38
Molecular Structure Molecular Structure of 2370-63-0 (2-ETHOXYETHYL METHACRYLATE) Hazard Symbols IrritantXi
Synonyms

Methacrylicacid, 2-ethoxyethyl ester (6CI,7CI,8CI);Ethanol, 2-ethoxy-, methacrylate(8CI);Acryester ET;Ethoxyethyl methacrylate;NSC24162;b-Ethoxyethyl methacrylate;

Article Data 6

2-Ethoxyethyl methacrylate Synthetic route

110-80-5

2-ethoxy-ethanol

920-46-7

Methacryloyl chloride

2370-63-0

2-ethoxyethyl methacrylate

Conditions
ConditionsYield
With pyridine In diethyl ether at 35℃; for 4h;77%
75-86-5

2-hydroxy-2-methylpropanenitrile

2370-63-0

2-ethoxyethyl methacrylate

Conditions
ConditionsYield
With sulfur trioxide; copper at 80 - 130℃; Zufuegen von Wasser, Kochen und folgendes Erhitzen des Reaktionsgemisches mit Aethylenglykol-monoaethylaether auf 100-110grad;
110-80-5

2-ethoxy-ethanol

80-62-6

methacrylic acid methyl ester

2370-63-0

2-ethoxyethyl methacrylate

Conditions
ConditionsYield
With sulfuric acid
With sodium 2-ethoxyethoxide
With sodium 2-ethoxyethoxide
110-80-5

2-ethoxy-ethanol

463-49-0

1,2-propanediene

201230-82-2

carbon monoxide

2370-63-0

2-ethoxyethyl methacrylate

Conditions
ConditionsYield
dodecacarbonyl-triangulo-triruthenium at 100℃; under 11400 Torr; for 3h;80 % Chromat.
17860-39-8

methyl 2-methoxy-2-methylpropanoate

2370-63-0

2-ethoxyethyl methacrylate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: anhydrous oxalic acid; hydroquinone
2: H2SO4
View Scheme
2370-63-0

2-ethoxyethyl methacrylate

92855-12-4

2-(naphthalen-1-yl)benzenamine

2-ethoxyethyl 2-((1-(2-aminophenyl)naphthalen-2-yl)methyl)acrylate

Conditions
ConditionsYield
With disodium hydrogenphosphate; (S)-STRIP; palladium diacetate; silver sulfate In toluene at 60℃; for 48h; Schlenk technique; stereoselective reaction;61%
2370-63-0

2-ethoxyethyl methacrylate

106-99-0

buta-1,3-diene

(Z)-2-Non-8-enyl-undeca-2,10-dienoic acid 2-ethoxy-ethyl ester

Conditions
ConditionsYield
With bis(acetylacetonate)nickel(II) In toluene
2370-63-0

2-ethoxyethyl methacrylate

106-99-0

buta-1,3-diene

(2E,5E)-2-Methyl-undeca-2,5,10-trienoic acid 2-ethoxy-ethyl ester

Conditions
ConditionsYield
With bis(acetylacetonate)nickel(II) In toluene
2370-63-0

2-ethoxyethyl methacrylate

80-62-6

methacrylic acid methyl ester

polymers (I)-(x)

polymers (I)-(x)

Conditions
ConditionsYield
With potassium peroxomonosulphate; sodium dodecyl-sulfate In cyclohexane; water at 60 - 70℃; for 3.5h; Product distribution; different ratios of monomers and solvent;

2,6-diphenyl-4-[4-(2-methylacryloyloxy)-phenyl]-pyrylium tetrafluoroborate

2370-63-0

2-ethoxyethyl methacrylate

polymer, radical copolymerization; monomer(s): 4-[4-(2-methyl-acryloyloxy)-phenyl]-2,6-diphenyl-pyranylium tetrafluoroborate; 2-ethoxyethyl methacrylate, molar ratio 0.5:100

polymer, radical copolymerization; monomer(s): 4-[4-(2-methyl-acryloyloxy)-phenyl]-2,6-diphenyl-pyranylium tetrafluoroborate; 2-ethoxyethyl methacrylate, molar ratio 0.5:100

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile); EDMA at 65℃; for 5h;

2-Ethoxyethyl methacrylate Specification

The 2-Ethoxyethyl methacrylate with cas registry number of 2370-63-0, belongs to the following product categories: (1)Acrylic Monomers; (2)C8 to C9Monomers; (3)Carbonyl Compounds; (4)Esters; (5)Methacrylate. Its systematic name and IUPAC name are the same, which is 2-ethoxyethyl 2-methylprop-2-enoate.

Physical properties about this chemical are: (1)ACD/LogP: 1.57; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 1.57; (4)ACD/LogD (pH 7.4): 1.57; (5)ACD/BCF (pH 5.5): 9.25; (6)ACD/BCF (pH 7.4): 9.25; (7)ACD/KOC (pH 5.5): 171.01; (8)ACD/KOC (pH 7.4): 171.01; (9)#H bond acceptors: 3; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 6; (12)Polar Surface Area: 35.53 Å2; (13)Index of Refraction: 1.424; (14)Molar Refractivity: 42.19 cm3; (15)Molar Volume: 165.3 cm3; (16)Polarizability: 16.72×10-24cm3; (17)Surface Tension: 27.9 dyne/cm; (18)Enthalpy of Vaporization: 41.87 kJ/mol; (19)Vapour Pressure: 0.812 mmHg at 25°C.

When you are using this chemical, please be cautious about it as the following:
The 2-Ethoxyethyl methacrylate irritates to eyes, respiratory system and skin. When use it, wear suitable protective clothing, gloves and eye/face protection. If contact with eyes, rinse immediately with plenty of water and seek medical advice. After use it, take off immediately all contaminated clothing.

You can still convert the following datas into molecular structure: 
(1)SMILES: O=C(OCCOCC)\C(=C)C;
(2)InChI: InChI=1/C8H14O3/c1-4-10-5-6-11-8(9)7(2)3/h2,4-6H2,1,3H3;
(3)InChIKey: SFPNZPQIIAJXGL-UHFFFAOYAD;
(4)Std. InChI: InChI=1S/C8H14O3/c1-4-10-5-6-11-8(9)7(2)3/h2,4-6H2,1,3H3;
(5)Std. InChIKey: SFPNZPQIIAJXGL-UHFFFAOYSA-N

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