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3-AMINOPROPIONITRILE

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Name

3-AMINOPROPIONITRILE

EINECS 205-786-0
CAS No. 151-18-8 Density 0.933 g/cm3
PSA 49.81000 LogP 0.55908
Solubility Soluble in water. Melting Point <25 °C
Formula C3H6N2 Boiling Point 186.324 °C at 760 mmHg
Molecular Weight 70.094 Flash Point 66.486 °C
Transport Information UN 3276 Appearance clear colourless to yellow liquid
Safety 36/37 Risk Codes 20/21/22
Molecular Structure Molecular Structure of 151-18-8 (3-Aminopropionitrile) Hazard Symbols HarmfulXn
Synonyms

Propionitrile,3-amino- (8CI);Propionitrile, b-amino- (4CI);1-Cyano-2-aminoethane;2-Cyanoethylamine;3-Aminopropanenitrile;Aminopropionitrile;BAPN;N-(2-Cyanoethyl)amine;NSC 40641;b-Alaninenitrile;b-Aminopropionitrile;b-Cyanoethylamine;

Article Data 44

3-AMINOPROPIONITRILE Synthetic route

107-13-1

acrylonitrile

151-18-8

2-cyanoethylamine

Conditions
ConditionsYield
With ammonia83%
With ammonia60%
With ammonia at 100℃; under 6750.68 Torr; for 4h; Temperature; Pressure;45%
67-56-1

methanol

107-13-1

acrylonitrile

A

151-18-8

2-cyanoethylamine

B

110-67-8

3-Methoxypropionitrile

C

107-12-0

propiononitrile

Conditions
ConditionsYield
With ammonia; hydrogen; chromium; cobalt; iron; nickel at 100℃; under 60004.8 Torr;A 65%
B 20%
C 15%
107-13-1

acrylonitrile

A

151-18-8

2-cyanoethylamine

B

111-94-4

3,3'-Iminodipropionitrile

Conditions
ConditionsYield
With ammonium hydroxide at 20℃; for 0.5h;A 30%
B 47%
With ammonia for 24h;A 12%
B n/a
With ammonia; water at 96℃; unter Wasserstoff-Druck;
497-25-6

dimethylenecyclourethane

151-18-8

2-cyanoethylamine

Conditions
ConditionsYield
With potassium cyanide; 18-crown-6 ether at 100℃; for 5h; Neat (no solvent);13%
542-76-7

3-Chloropropionitrile

151-18-8

2-cyanoethylamine

Conditions
ConditionsYield
With ammonia at 21 - 24℃; under 5884.06 - 7355.08 Torr;
111-94-4

3,3'-Iminodipropionitrile

151-18-8

2-cyanoethylamine

Conditions
ConditionsYield
under 735.5 Torr; durch Destillation;
under 735.5 Torr; Destillation;
34583-60-3

p-CH3C6H4-O2SO-CH2CH2CN

151-18-8

2-cyanoethylamine

Conditions
ConditionsYield
(i) bis-(4-chloro-phenylsulfanyl)-amine <li salt="">, THF, (ii) PhSH, ZnCl2</li>; Multistep reaction;
1119-50-2

3-acetylaminopropionitrile

A

151-18-8

2-cyanoethylamine

B

64-19-7

acetic acid

Conditions
ConditionsYield
With hydrogenchloride In water at 30℃; Rate constant; hydrolysis;
352-96-5

3-aminopropionitrile fumarate salt

151-18-8

2-cyanoethylamine

Conditions
ConditionsYield
With sodium hydroxide In water

(2-Cyano-ethyl)-thiocarbamic acid; compound with triethyl-amine

A

463-58-1

carbon oxide sulfide

B

151-18-8

2-cyanoethylamine

Conditions
ConditionsYield
With phosphate buffer In water at 25℃; Mechanism; Rate constant; general acid catalysis;

3-AMINOPROPIONITRILE Chemical Properties

IUPAC Name: 3-Aminopropionitrile
The MF of 3-Aminopropionitrile (151-18-8) is C3H6N2.

                         
The MW of 3-Aminopropionitrile (151-18-8) is 70.09.
Synonyms of 3-Aminopropionitrile (151-18-8): 3-Aminopropionitrile ; 2-Cyanoethylamine ; Propanenitrile, 3-amino-
Form: clear colourless to yellow liquid
Index of Refraction: 1.429 
EINECS: 205-786-0 
Density: 0.933 g/ml 
Flash Point: 66.5 °C 
Boiling Point: 186.3 °C
Storage temp: Refrigerator
Merck: 14,469
BRN: 1698848

3-AMINOPROPIONITRILE Uses

   3-Aminopropionitrile (151-18-8) is used for organic synthesis, pharmaceutical intermediates.

3-AMINOPROPIONITRILE Toxicity Data With Reference

1.    

sce-mus:emb 1250 mg/kg

    ARTODN    Archives of Toxicology. 47 (1981),305.
2.    

skn-mus LDLo:12,800 mg/kg

    EMPSAL    Experimental and Molecular Pathology, Supplement. 39 (1983),154.
3.    

ipr-mus LD50:1152 mg/kg

    EMPSAL    Experimental and Molecular Pathology, Supplement. 39 (1983),154.

3-AMINOPROPIONITRILE Consensus Reports

EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory. Cyanide and its compounds are on the Community Right-To-Know List.

3-AMINOPROPIONITRILE Safety Profile

Moderately toxic by intraperitoneal route. An experimental teratogen. Other experimental reproductive effects. Mutation data reported. Nitriles usually have cyanide-like effects. See also CYANIDE. Easily oxidized and unstable. A storage hazard; it polymerizes to an explosive yellow solid. When heated to decomposition it emits toxic fumes of CN and NOx. For fire and explosion hazards see CYANIDE.
Safety information of 3-Aminopropionitrile (151-18-8):
Hazard Codes  Xn
Risk Statements 
20/21/22  Harmful by inhalation, in contact with skin and if swallowed
Safety Statements 
36/37  Wear suitable protective clothing and gloves
RIDADR  3276
RTECS  UG0350000
HazardClass  8
PackingGroup  III

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