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Cas Database |
| Name |
3-Allyloxy-1,2-Propanediol |
EINECS | 204-620-4 |
| CAS No. | 123-34-2 | Density | 1.068 g/mL at 25 °C(lit.) |
| PSA | 49.69000 | LogP | -0.45780 |
| Solubility | soluble in water | Melting Point |
-100 °C |
| Formula | C6H12 O3 | Boiling Point | 142 °C28 mm Hg(lit.) |
| Molecular Weight | 132.159 | Flash Point | 132 °C |
| Transport Information | N/A | Appearance | clear, colorless liquid. |
| Safety | Moderately toxic by ingestion and subcutaneous routes. A skin and eye irritant. See also ETHERS and ALLYL COMPOUNDS. When heated to decomposition it emits acrid smoke and irritating fumes. | Risk Codes | 36 |
| Molecular Structure |
|
Hazard Symbols |
 Xi
|
| Synonyms |
1,2-Propanediol,3-(2-propenyloxy)- (9CI); 1,2-Propanediol, 3-(allyloxy)- (6CI,7CI,8CI);1-(Allyloxy)-2,3-propanediol; 1-Allyloxy-2,3-dihydroxypropane;3-(2-Propenyloxy)-1,2-propanediol; 3-(Allyloxy)-1,2-propanediol; Glycerin1-allyl ether; Glycerol 1-allyl ether; Glycerol 1-monoallyl ether; Glycerol a-allyl ether; Glycerol a-monoallyl ether; NSC 59722 |
Article Data | 80 |
3-Allyloxy-1,2-Propanediol Chemical Properties
Chemistry informtion about 3-Allyloxy-1,2-Propanediol (CAS NO.123-34-2) is:
IUPAC Name: 3-Prop-2-Enoxypropane-1,2-Diol
Synonyms: 1-(Prop-2-Enyloxy)-Propane-2,3-Diol ; 1,2-Propanediol, 3-(2-Propenyloxy)- ; 1,2-Propanediol, 3-(Allyloxy)- ; 1-Allyloxy-2,3-Propanediol ; 2-Propanediol,3-(2-Propenyloxy)-1 ; 3-(2-Propenyloxy)-2-Propanediol ; 3-(Allyloxy)Propanediol ; 3-Allyloxy-2-Propanediol
MF: C6H12O3
MW: 132.16
EINECS: 204-620-4
Density: 1.062 g/cm3
Melting Point: -100 °C
Flash Point: 107 °C
Boiling Point: 234.1 °C at 760 mmHg
Vapour Pressure: 0.00991 mmHg at 25°C
Enthalpy of Vaporization: 54.73 kJ/mol
Refractive Index: n20/D 1.462(lit.)
Following is the molecular structure of 3-Allyloxy-1,2-Propanediol (CAS NO.123-34-2) is:
3-Allyloxy-1,2-Propanediol Uses
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| mammal (species unspecified) | LD50 | oral | > 5gm/kg (5000mg/kg) | Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 39(4), Pg. 86, 1974. | |
| mouse | LD50 | oral | 4200mg/kg (4200mg/kg) | peripheral nerve and sensation: flaccid paralysis without anesthesia (usually neuromuscular blockage) behavioral: altered sleep time (including change in righting reflex) lungs, thorax, or respiration: respiratory depression | Federation Proceedings, Federation of American Societies for Experimental Biology. Vol. 8, Pg. 477, 1949. |
| mouse | LD50 | subcutaneous | 1135mg/kg (1135mg/kg) | peripheral nerve and sensation: flaccid paralysis without anesthesia (usually neuromuscular blockage) behavioral: muscle weakness lungs, thorax, or respiration: other changes | Journal of Pharmacology and Experimental Therapeutics. Vol. 93, Pg. 470, 1948. |
3-Allyloxy-1,2-Propanediol Toxicity Data With Reference
| 1. | skn-rbt 535 mg/24H MLD | |||
| 2. |
| AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. 2 (1950),574. | ||
| 3. | eye-rbt 107 mg | AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. 2 (1950),574. | ||
| 4. | eye-rbt 100 mg/24H MOD | 85JCAE Prehled Prumyslove Toxikologie; Organicke Latky Marhold, J.,Prague, Czechoslovakia,Avicenum.: 1986,632. | ||
| 5. | orl-mus LD50:4200 mg/kg | FEPRA7 Federation Proceedings, Federation of American Societies for Experimental Biology. 8 (1949),477. | ||
| 6. | scu-mus LD50:1135 mg/kg | JPETAB Journal of Pharmacology and Experimental Therapeutics. 93 (1948),470. |
3-Allyloxy-1,2-Propanediol Consensus Reports
Reported in EPA TSCA Inventory.
3-Allyloxy-1,2-Propanediol Safety Profile
Moderately toxic by ingestion and subcutaneous routes. A skin and eye irritant. See also ETHERS and ALLYL COMPOUNDS. When heated to decomposition it emits acrid smoke and irritating fumes.
Hazard Codes:
Xi
Risk Statements:
R36:Irritating to eyes.
Safety Statements:
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
WGK Germany: 1
RTECS: TY2700000
3-Allyloxy-1,2-Propanediol Specification
3-Allyloxy-1,2-Propanediol (CAS NO.123-34-2) is a clear colorless to light yellow viscous liquid.
First Aid Measures:
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids.
Skin: Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion: Do not induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation: Remove from exposure and move to fresh air immediately.
Handling and Storage:
Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.
Storage: Store in a cool, dry place. Keep container closed when not in use.
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