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Name |
3-Hydroxybenzaldehyde |
EINECS | 202-892-9 |
CAS No. | 100-83-4 | Density | 1.226 g/cm 3 |
PSA | 37.30000 | LogP | 1.20470 |
Solubility | soluble in water | Melting Point |
100-103 °C(lit.) |
Formula | C7H6O2 | Boiling Point | 240.9 °C at 760 mmHg |
Molecular Weight | 122.123 | Flash Point | 98.6 °C |
Transport Information | N/A | Appearance | off-white solid |
Safety | 26-36-24/25 | Risk Codes | 36/37/38 |
Molecular Structure | Hazard Symbols | Xi | |
Synonyms |
meta-Hydroxybenzaldehyde;Benzaldehyde, 3-hydroxy-;m-Formylphenol;3-Formylphenol;3-hydroxyBenzaldehyde;m-hydroxyBenzaldehyde;m-hydroxybenzaldehyde;Benzaldehyde, m-hydroxy-; |
Article Data | 172 |
Conditions | Yield |
---|---|
With silica gel; 4-acetylamino-2,2,6,6-tetramethylpiperidine-1-oxoammonium perchlorate In dichloromethane | 100% |
With manganese(IV) oxide; manganese(II) nitrate tetrahydrate; dibenzoyl peroxide In hexane at 70℃; under 760.051 Torr; for 0.0833333h; chemoselective reaction; | 99% |
In neat (no solvent) at 20℃; for 0.0333333h; Microwave irradiation; | 99% |
meta-hydroxybenzaldehyde
Conditions | Yield |
---|---|
With hydrogenchloride for 0.0416667h; Product distribution; Ambient temperature; pH = 4-6, regeneration of aldehyde; | 100% |
Conditions | Yield |
---|---|
With iron(III) chloride on silica In neat (no solvent) at 80℃; for 0.5h; | 99% |
With magnesium iodide for 5h; neat (no solvent); | 93% |
3-(tert-butyl-dimethyl-sylanyloxy)benzaldehyde
meta-hydroxybenzaldehyde
Conditions | Yield |
---|---|
With lithium acetate In water; N,N-dimethyl-formamide at 25℃; for 8h; Inert atmosphere; | 96% |
With triethylamine N-oxide In methanol for 1h; | 91% |
In water; dimethyl sulfoxide at 90℃; for 8h; | 87% |
2-(3-hydroxyphenyl)-1,3-dithiolane
meta-hydroxybenzaldehyde
Conditions | Yield |
---|---|
With ammonium iodide; dihydrogen peroxide; sodium dodecyl-sulfate In water at 20℃; for 1h; micellar medium; | 96% |
With 2,4,4,6-Tetrabromo-2,5-cyclohexadien-1-one; dihydrogen peroxide In water; acetonitrile at 20℃; for 1h; | 94% |
With dihydrogen peroxide; iodine; sodium dodecyl-sulfate In water at 20℃; for 3h; Micellar solution; | 90% |
2-(3-hydroxyphenyl)-1,3-dithiane
meta-hydroxybenzaldehyde
Conditions | Yield |
---|---|
With dihydrogen peroxide; iodine; sodium dodecyl-sulfate In water at 20℃; for 0.666667h; Micellar solution; | 95% |
With acetic acid at 25℃; for 15h; | 51% |
3-benzenesulfonyloxy-benzaldehyde
meta-hydroxybenzaldehyde
Conditions | Yield |
---|---|
With potassium hydroxide In toluene; tert-butyl alcohol at 100℃; for 0.5h; Inert atmosphere; | 95% |
3-Formylphenylboronic acid
meta-hydroxybenzaldehyde
Conditions | Yield |
---|---|
With C100H52N4O16Sn(6-)*2In(3+); N-ethyl-N,N-diisopropylamine In N,N-dimethyl-formamide for 3.5h; Irradiation; | 94% |
With C18H28Cl2CuN2O4 In water at 26℃; for 0.333333h; | 92% |
With 10-methylacridine-3(10H)-one; oxygen; N-ethyl-N,N-diisopropylamine In water at 20℃; for 20h; Irradiation; Green chemistry; | 90% |
3-allyloxy-benzaldehyde
meta-hydroxybenzaldehyde
Conditions | Yield |
---|---|
With bis(benzonitrile)palladium(II) dichloride In benzene for 20h; Heating; | 92% |
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In methanol at 20℃; for 6h; | 82% |
3-((triisopropylsilyl)oxy)benzaldehyde
meta-hydroxybenzaldehyde
Conditions | Yield |
---|---|
With potassium acetate In water; N,N-dimethyl-formamide at 25℃; for 13h; | 92% |
1. | sce-hmn:lyms 1 mmol/L | MUREAV Mutation Research. 206 (1988),17. |