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6,7-Dimethoxy-2-tetralone

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Name

6,7-Dimethoxy-2-tetralone

EINECS N/A
CAS No. 2472-13-1 Density 1.14 g/cm3
PSA 35.53000 LogP 1.76160
Solubility N/A Melting Point 87-89 °C(lit.)
Formula C12H14O3 Boiling Point 348 °C at 760 mmHg
Molecular Weight 206.241 Flash Point 155.5 °C
Transport Information N/A Appearance N/A
Safety Risk Codes N/A
Molecular Structure Molecular Structure of 2472-13-1 (6,7-Dimethoxy-2-tetralone) Hazard Symbols N/A
Synonyms

3,4-Dihydro-6,7-dimethoxy-2(1H)-naphthalenone;6,7-Dimethoxy-3,4-dihydro-1H-naphthalen-2-one;6,7-Dimethoxy-b-tetralone;

Article Data 3

6,7-Dimethoxy-2-tetralone Specification

The systematic name of 6,7-dimethoxy-3,4-dihydronaphthalen-2(1H)-one is 6,7-Dimethoxy-2-tetralone . With the CAS registry number 2472-13-1, it is also named as 2(1H)-naphthalenone, 3,4-dihydro-6,7-dimethoxy- ; 6,7-Dimethoxy-3,4-dihydro-2(1H)-naphthalenone ; 6,7-Dimethoxy-3,4-dihydro-1H-naphthalen-2-one . 

The 6,7-Dimethoxy-2-tetralone can be obtained by many meyhods. For example: 1. it can be prepared by 3-(4,5-dimethoxy-2-methoxycarbonylmethyl-phenyl)-propionic acid methyl ester with KO-tert-Bu , LiCl , HCl and H2O. The solvent are diethyl ether and dimethylsulfoxide . The reaction type contains condensation, dieckmann reaction, hydrolysis and decarboxylation.

2. The 6,7-Dimethoxy-2-tetralone can be prepared by 5,6-dimethoxy-2,3-dihydro-1aH-1-oxa-cyclopropa[a]naphthalene-7b-carboxylic acid amide .

The 6,7-Dimethoxy-2-tetralone can be used in organic synthesis. It can used to synthesize other chemicals. For example: it can reacts with trifluoro-methanesulfonic acid anilide to get trifluoro-methanesulfonic acid 6,7-dimethoxy-3,4-dihydro-naphthalen- ; it reacts with hydrocyanic acid; potassium salt to get 6',7'-dimethoxy-3',4'-dihydro-1'H-spiro[imidazolidine-4,2'-naphthalene]-2,5-dione ; it reacts with propylamine and methyl 2-(bromomethyl)acrylate to get methyl 4-n-propyl-8,9-dimethoxy-1,2,3,4,5,6-hexahydrobenzo[f]quinoline-2-carboxylate .

The other characteristics of this product can be summarized as: (1)H bond acceptors: 3 ; (2)H bond donors: 0 ; (3)#Freely Rotating Bonds: 2 ; (4)Index of Refraction: 1.537 ; (5)Molar Refractivity: 56.52 cm3 ; (6)Molar Volume: 180.7 cm3 ; (7)Polarizability: 22.4×10-24 cm3 ; (8)Surface Tension: 40.1 dyne/cm ; (9)Enthalpy of Vaporization: 59.24 kJ/mol ; (10)Vapour Pressure: 5.17E-05 mmHg at 25°C.People can use the following data to convert to the molecule structure. SMILES: O=C2Cc1c(cc(OC)c(OC)c1)CC2; InChI: InChI=1/C12H14O3/c1-14-11-6-8-3-4-10(13)5-9(8)7-12(11)15-2/h6-7H,3-5H2,1-2H3.

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