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Cas Database |
| Name |
7-Tetradecenal, (7Z)- |
EINECS | 265-493-9 |
| CAS No. | 65128-96-3 | Density | 0.839 g/cm3 |
| PSA | 17.07000 | LogP | 4.66240 |
| Solubility | N/A | Melting Point |
N/A |
| Formula | C14H26O | Boiling Point | 297.4 °C at 760 mmHg |
| Molecular Weight | 210.36 | Flash Point | 137.9 °C |
| Transport Information | N/A | Appearance | colorless to pale yellow liquid |
| Safety | 26-36 | Risk Codes | 36/37/38 |
| Molecular Structure |
|
Hazard Symbols | Xi |
| Synonyms |
7-Tetradecenal,(Z)-;(Z)-7-Tetradecenal;cis-7-Tetradecenal; |
Article Data | 5 |
7-Tetradecenal, (7Z)- Synthetic route
- 83807-44-7, 83860-43-9
cis-7,8-epoxy-14(Z)-heneicosene
- 65128-96-3
(Z)-7-tetradecenal
| Conditions | Yield |
|---|---|
| With periodic acid In diethyl ether at 0℃; for 1.5h; | 82% |
- 37011-94-2
7-tetradecyne-1-ol
- 65128-96-3
(Z)-7-tetradecenal
| Conditions | Yield |
|---|---|
| Yield given. Multistep reaction; | |
| Multi-step reaction with 2 steps 1: H2 / Lindlar's catalyst / hexane / 9 h / 20 °C 2: 8.7 g / (COCl)2; DMSO; Et3N / CH2Cl2 / 1 h / 0 °C View Scheme |
- 40642-43-1
(Z)-tetradec-7-en-1-ol
- 65128-96-3
(Z)-7-tetradecenal
| Conditions | Yield |
|---|---|
| With pyridium chlorochromate In dichloromethane at 20℃; for 3h; Yield given; | |
| With dipyridinium dichromate In dichloromethane for 2h; | |
| With oxalyl dichloride; dimethyl sulfoxide; triethylamine In dichloromethane at 0℃; for 1h; | 8.7 g |
- 37043-40-6
2-(tetradec-7-yn-1-yloxy)tetrahydro-2H-pyran
- 65128-96-3
(Z)-7-tetradecenal
| Conditions | Yield |
|---|---|
| Multi-step reaction with 3 steps 1: 47.7 g / D-10-camphorsulfonic acid / methanol / 24 h / 20 °C 2: H2 / Lindlar's catalyst / hexane / 9 h / 20 °C 3: 8.7 g / (COCl)2; DMSO; Et3N / CH2Cl2 / 1 h / 0 °C View Scheme |
- 53963-10-3
2-[(6-bromohexyl)oxy]tetrahydro-2H-pyran
- 65128-96-3
(Z)-7-tetradecenal
| Conditions | Yield |
|---|---|
| Multi-step reaction with 4 steps 1.1: n-BuLi / tetrahydrofuran; hexane / 0.17 h / 0 °C 1.2: hexamethylphosphoric triamide (HMPA) / tetrahydrofuran; hexane / 22 h / 20 °C 2.1: 47.7 g / D-10-camphorsulfonic acid / methanol / 24 h / 20 °C 3.1: H2 / Lindlar's catalyst / hexane / 9 h / 20 °C 4.1: 8.7 g / (COCl)2; DMSO; Et3N / CH2Cl2 / 1 h / 0 °C View Scheme |
| Conditions | Yield |
|---|---|
| Multi-step reaction with 4 steps 1.1: n-BuLi / tetrahydrofuran; hexane / 0.17 h / 0 °C 1.2: hexamethylphosphoric triamide (HMPA) / tetrahydrofuran; hexane / 22 h / 20 °C 2.1: 47.7 g / D-10-camphorsulfonic acid / methanol / 24 h / 20 °C 3.1: H2 / Lindlar's catalyst / hexane / 9 h / 20 °C 4.1: 8.7 g / (COCl)2; DMSO; Et3N / CH2Cl2 / 1 h / 0 °C View Scheme |
- 65128-96-3
(Z)-7-tetradecenal
- 139623-13-5
(R)-1,3-dihydroxytetradecane
- 592543-36-7
(2S,4R)-4-undecyl-2-[(Z)-tridec-6-enyl]-1,3-dioxane
| Conditions | Yield |
|---|---|
| With camphor-10-sulfonic acid In benzene at 50℃; under 70 Torr; for 2h; | 100% |
- 65128-96-3
(Z)-7-tetradecenal
- 2430-95-7
(7Z)-tetradec-7-enic acid
| Conditions | Yield |
|---|---|
| With sodium chlorite; sodium dihydrogenphosphate; 2-methyl-but-2-ene In tert-butyl alcohol at 20℃; for 3h; | 96% |
- 1067-74-9
Methyl diethylphosphonoacetate
- 65128-96-3
(Z)-7-tetradecenal
- 158420-87-2
methyl (2E,9Z)-hexadeca-2,9-dienoate
| Conditions | Yield |
|---|---|
| With sodium hydride In tetrahydrofuran at 20℃; for 2.5h; | 92% |
7-Tetradecenal, (7Z)- Specification
This chemical is called 7-Tetradecenal, (7Z)-, and its systematic name is (7Z)-tetradec-7-enal. With the molecular formula of C14H26O, its molecular weight is 210.36. The CAS registry number of this chemical is 65128-96-3.
Other characteristics of the 7-Tetradecenal, (7Z)- can be summarised as followings: (1)ACD/LogP: 5.70; (2)# of Rule of 5 Violations: 1; (3)#H bond acceptors: 1; (4)#H bond donors: 0; (5)#Freely Rotating Bonds: 11; (6)Polar Surface Area: 17.07 Å2; (7)Index of Refraction: 1.448; (8)Molar Refractivity: 67.15 cm3; (9)Molar Volume: 250.5 cm3; (10)Polarizability: 26.62×10-24cm3; (11)Surface Tension: 29.7 dyne/cm; (12)Density: 0.839 g/cm3; (13)Flash Point: 137.9 °C; (14)Enthalpy of Vaporization: 53.73 kJ/mol; (15)Boiling Point: 297.4 °C at 760 mmHg; (16)Vapour Pressure: 0.00135 mmHg at 25°C.
You can still convert the following datas into molecular structure:
1.SMILES: O=CCCCCC\C=C/CCCCCC
2.InChI: InChI=1/C14H26O/c1-2-3-4-5-6-7-8-9-10-11-12-13-14-15/h7-8,14H,2-6,9-13H2,1H3/b8-7-
3.InChIKey: AVHNDAZRNRAYTP-FPLPWBNLBX
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