ALLYL GLYCIDYL ETHER (106-92-3),ALLYL GLYCIDYL ETHER (106-92-3) Manufacturers & Suppliers,Synthesis,MSDS

Basic information

Name:
Oxirane,2-[(2-propen-1-yloxy)methyl]-
Superlist Name:
Allyl glycidyl ether
CAS No.:
106-92-3
Molecular Structure:
Formula:
C₆H₁₀O₂
Molecular Weight:
114.16
Deleted CAS:
90907-93-0|112186-06-8
Synonyms:
Oxirane,[(2-propenyloxy)methyl]- (9CI);Propane, 1-(allyloxy)-2,3-epoxy- (6CI,8CI);1,2-Epoxy-3-allyloxypropane;1-(2-Propenyloxy)-2,3-epoxypropane;1-Allyloxy-2,3-epoxypropane;2-(Allyloxymethyl)oxirane;2-[[(2-Propenyl)oxy]methyl]oxirane;AGE;Allyl 2,3-epoxypropyl ether;Allyl oxiranemethyl ether;Denacol EX 111;Glycidyl2-propenyl ether;Glycidyl allyl ether;NSC 18596;NSC 631;[(2-Propenyloxy)methyl]oxirane;[(Allyloxy)methyl]oxirane;
EINECS:
203-442-4
Density:
0.962 g/cm³
Melting Point:
-100 °C
Boiling Point:
153.2 °C at 760 mmHg
Flash Point:
57.2 °C
Solubility:
50 g/L (20 °C) in water
Appearance:
colourless liquid
Hazard Symbols:
Xn
Risk Codes:
10-20/22-37/38-40-41-43-52/53-62-68
Safety Description:
24/25-26-36/37/39-61 Details
Transport Information:
UN 2219 3/PG 3

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Consensus Reports

Reported in EPA TSCA Inventory.

Standards and Recommendations

OSHA PEL: TWA 5 ppm; STEL 10 ppm
ACGIH TLV: 1 ppm; Not Classifiable as a Human Carcinogen
DFG MAK: Confirmed Animal Carcinogen, Suspected Human Carcinogen
NIOSH REL: (Glycidyl Ethers) CL 45 mg/m³/15M
DOT Classification: 3; Label: Flammable Liquid, Poison

Analytical Methods

For occupational chemical analysis use NIOSH: Allyl Glycidyl Ether S346.

Specification

The Allyl glycidyl ether, with the cas register number 106-92-3, has the systematic name of 2-[(prop-2-en-1-yloxy)methyl]oxirane. And its product categories of Industrial/Fine Chemicals; Simple 3-Membered Ring Compounds; Oxiranes.

The basic information of this chemical is below: This is a kind of colourless liquid, and it is insoluble in water and is flammable. And this is stable but incompatible with strong oxidizing agents, acids, bases. May form peroxides in storage if in contact with air. When store it, this chemical should be stored in the temp. Refrigerator (+4°C), and away from the oxidizing agent.

The characteristics of this chemical are as following: (1)ACD/LogP: 0.78; (2)ACD/LogD (pH 5.5): 0.78; (3)ACD/LogD (pH 7.4): 0.78; (4)ACD/BCF (pH 5.5): 2.3; (5)ACD/BCF (pH 7.4): 2.3; (6)ACD/KOC (pH 5.5): 63.18; (7)ACD/KOC (pH 7.4): 63.18; (8)#H bond acceptors: 2; (9)#Freely Rotating Bonds: 4; (10)Polar Surface Area: 21.76; (11)Index of Refraction: 1.443; (12)Molar Refractivity: 30.89 cm³; (13)Molar Volume: 116.3 cm³; (14)Polarizability: 12.24 ×10^-24 cm³; (15)Surface Tension: 32.1 dyne/cm; (16)Density: 0.981 g/cm³; (17)Flash Point: 57.2 °C; (18)Enthalpy of Vaporization: 37.39 kJ/mol; (19)Boiling Point: 153.2 °C at 760 mmHg; (20)Vapour Pressure: 4.32 mmHg at 25°C.

Use of Allyl glycidyl ether: Allyl glycidyl ether could react with 7(9)H-purin-6-ylamine to produce 1-allyloxy-3-(6-amino-purin-9-yl)-propan-2-ol, in the following condtion: reagent: K2CO3; solvent: dimethylsulfoxide; reaction time: 5 days; field: 40%; other condition: Ambient temperature.

When you deal with this chemical, you should be very cautious. Being a kind of harmful chemical, it may cause damage to health, and if by inhalation or if swallowed, it will be very harmful. Then it may even have limited evidence of a carcinogenic effect and has possible risk of impaired fertility. Besides, it is irritating to respiratory system and skin and it may cause sensitisation by skin contact. What's more, it is harmful to aquatic organisms, and it may cause long-term adverse effects in the aquatic environment. Then it has possible risk of irreversible effects. So you should take the following instructions while using. Wear suitable protective clothing, gloves and eye/face protection, and avoid contacting with skin and eyes. If in case of contacting with eyes, rinse immediately with plenty of water and seek medical advice. Besides, avoid releasing to the environment and then refer to special instructions/safety data sheet.

In addition, you could convert the following datas into the molecular structure：
SMILES: C=CCOCC1CO1Copy

Below are the toxicity information of this chemical:

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
mouse	LC50	inhalation	270ppm/4H (270ppm)	SENSE ORGANS AND SPECIAL SENSES: LACRIMATION: EYE LUNGS, THORAX, OR RESPIRATION: DYSPNEA GASTROINTESTINAL: CHANGES IN STRUCTURE OR FUNCTION OF SALIVARY GLANDS	AMA Archives of Industrial Health. Vol. 14, Pg. 250, 1956.
mouse	LD50	oral	390mg/kg (390mg/kg)	BRAIN AND COVERINGS: RECORDINGS FROM SPECIFIC AREAS OF CNS BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) BEHAVIORAL: ATAXIA	AMA Archives of Industrial Health. Vol. 14, Pg. 250, 1956.
rabbit	LD50	skin	2550mg/kg (2550mg/kg)		AMA Archives of Industrial Health. Vol. 14, Pg. 250, 1956.
rat	LC50	inhalation	670ppm/8H (670ppm)	SENSE ORGANS AND SPECIAL SENSES: CORNEAL DAMAGE: EYE LUNGS, THORAX, OR RESPIRATION: ACUTE PULMONARY EDEMA GASTROINTESTINAL: CHANGES IN STRUCTURE OR FUNCTION OF SALIVARY GLANDS	AMA Archives of Industrial Health. Vol. 14, Pg. 250, 1956.
rat	LD50	oral	1600mg/kg (1600mg/kg)	BRAIN AND COVERINGS: RECORDINGS FROM SPECIFIC AREAS OF CNS BEHAVIORAL: CHANGES IN MOTOR ACTIVITY (SPECIFIC ASSAY) BEHAVIORAL: ATAXIA	AMA Archives of Industrial Health. Vol. 14, Pg. 250, 1956.