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Name	Acrylamide	EINECS	201-173-7
CAS No.	79-06-1	Density	0.961 g/cm³
PSA	43.09000	LogP	0.35800
Solubility	soluble in water	Melting Point	82-86 °C(lit.)
Formula	C₃H₅NO	Boiling Point	231.711 °C at 760 mmHg
Molecular Weight	71.0788	Flash Point	78.951 °C
Transport Information	UN 3426 6.1/PG 3	Appearance	white crystals
Safety	53-45-24-36/37/39-26-36/37	Risk Codes	45-46-20/21-25-36/38-43-48/23/24/25-62-48/20/21/22-22-24/25
Molecular Structure		Hazard Symbols	T
Synonyms	Acrylamide(8CI);Acrylic amide;Bio-Acrylamide 50;Ethylenecarboxamide;NSC 7785;Propenamide;Vinyl amide;	Article Data	195

Acrylamide Synthetic route

: 107-13-1
acrylonitrile

: 79-06-1
2-propenamide

Conditions

Conditions	Yield
With amorphous Cu-Ti alloy; hydrogen fluoride Product distribution; other Cu alloys or Cu metal, absence HF;	100%
With water; aluminum oxide; Ru(OH)x at 119.85℃; for 24h;	100%
With water; copper chromite, reduced, supported in stainless steel wire socks at 64 - 96℃; under 637.564 Torr; Heating / reflux;	100%

: 107-13-1
acrylonitrile

A: 79-06-1
2-propenamide

B: 79-10-7
acrylic acid

Conditions

Conditions	Yield
With water at 0 - 4℃; for 7.5h; culture broth containing cells of Pseudomonas chlororaphis, strain B23;	A 99% B 0.7%
With water; copper oxide, reduced, supported in stainless steel wire socks at 135 - 158℃; under 3760.13 Torr; Heating / reflux;

: 3130-87-8
ASPARAGINE

: 131543-46-9
Glyoxal

: 79-06-1
2-propenamide

Conditions

Conditions	Yield
With deglycase DJ-1 at 70℃; Reagent/catalyst; Temperature; Enzymatic reaction;	98%

: 107-02-8
acrolein

: 79-06-1
2-propenamide

Conditions

Conditions	Yield
With choline chloride * 2ZnCl2; hydroxylamine hydrochloride at 80℃; for 15h; Green chemistry;	91%
With hydroxylamine In water at 110℃; for 12h;	76%
With hydroxylamine In water at 110℃; for 12h;	76%

: 107-13-1
acrylonitrile

: 115-11-7
isobutene

A: 107-58-4
N-tert-Butylacrylamide

B: 15214-89-8
2-acrylamido-2-methylpropanesulfonic acid

C: 79-06-1
2-propenamide

Conditions

Conditions	Yield
With sulfuric acid at 20℃; for 2h;	A n/a B 87% C n/a

: 1147-43-9
2-(2-aminobenzoyl)benzoic acid

: 7732-18-5
water

: 814-68-6
acryloyl chloride

A: 2-acrylaminobenzophenone-2'-carboxylic acid

B: 79-06-1
2-propenamide

Conditions

Conditions	Yield
With hydrogenchloride; sodium hydroxide In ethanol	A 86% B n/a

: 67969-82-8
tetrafluoroboric acid diethyl ether

: F6P(1-)*C27H44Fe2NOS2(1+)

: 107-13-1
acrylonitrile

A: F6P(1-)*C30H46Fe2N2S2(2+)*BF4(1-)

B: 79-06-1
2-propenamide

Conditions

Conditions	Yield
In acetone at 20℃; for 2h; Inert atmosphere; Schlenk technique;	A 85% B 86%

: 4441-33-2
3-(morpholin-4-yl)propionamide

: 108-24-7
acetic anhydride

A: 1696-20-4
4-acetylmorpholine

B: 79-06-1
2-propenamide

Conditions

Conditions	Yield
Stage #1: 3-(morpholin-4-yl)propionamide; acetic anhydride In toluene at 20 - 80℃; for 2h; Inert atmosphere; Stage #2: With 2,6-di-tert-butyl-4-methyl-phenol; triethylamine Reagent/catalyst; Reflux;	A 84% B 86%

›PtCl(PMe2 OH)(PMe2 O)2[H]: ›PtCl(PMe2 OH)(PMe2 O)2[H]

: 107-13-1
acrylonitrile

: 79-06-1
2-propenamide

Conditions

Conditions	Yield
In ethanol; water	83%

: ammonium 3-hydroxypropionate

A: 79-06-1
2-propenamide

B: acrylic acid ammonium salt

C: 503-66-2
3-hydroxypropionic acid

Conditions

Conditions	Yield
With ammonia; Ti-0720 (Engelhard) catalyst In water at 200 - 250℃; for 37h; Product distribution / selectivity;	A n/a B 75% C n/a
titanium catalyst In water at 180℃; for 37h; Product distribution / selectivity;	A 1.5% B 65% C n/a
titanium catalyst In water at 180℃; for 37h; Product distribution / selectivity;	A 1.5% B 65% C n/a

Acrylamide Chemical Properties

Product Name: Acrylamide (CAS NO.79-06-1)

Molecular Formula: C₃H₅NO
Molecular Weight: 71.08g/mol
Mol File: 79-06-1.mol
EINECS: 201-173-7
Melting Point: 82-86 °C(lit.)
Boiling point: 231.7 °C at 760 mmHg
Storage Temperature: 2-8°C
Flash Point: 79 °C
Density: 0.961 g/cm³
Refractive index: 1.460
Water Solubility: H₂O: 50 mg/mL at 20 °C, clear, colorless
Sensitive: Light Sensitive
Stability: Unstable. Do not heat above 50C. Explosive. Incompatible with acids, bases, oxidizing agents, reducing agents, iron and iron salts, copper, aluminium, brass, free radical initiators. Air sensitive. Hygroscopic.
Index of Refraction: 1.433
Molar Refractivity: 19.23 cm³
Molar Volume: 73.9 cm³
Surface Tension: 31 dyne/cm
Enthalpy of Vaporization: 46.84 kJ/mol
Vapour Pressure: 0.0614 mmHg at 25°C
XLogP3-AA: -0.7
H-Bond Donor: 1
H-Bond Acceptor: 1
Structure Descriptors of Acrylamide (CAS NO.79-06-1):
IUPAC Name: prop-2-enamide
Canonical SMILES: C=CC(=O)N
InChI: InChI=1S/C3H5NO/c1-2-3(4)5/h2H,1H2,(H2,4,5)
InChIKey: HRPVXLWXLXDGHG-UHFFFAOYSA-N
Product Categories: Industrial/Fine Chemicals; Acrylamide; Reagents for Electrophoresis; Biochemistry; Water Ttreatment Chemicals; AcrylamidesGlycobiology; Electrophoresis of Glycans; Glycan Labeling and Analysis; Protein Electrophoresis; SDS-PAGE; Biochemicals; Molecular Biology; Molecular Biology Reagents

Acrylamide Uses

Acrylamide (CAS NO.79-06-1) is used for sewage and waste treatment and it is also used to make dyes, adhesives.

Acrylamide Toxicity Data With Reference

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
guinea pig	LD50	oral	150mg/kg (150mg/kg)		Toxicology and Applied Pharmacology. Vol. 6, Pg. 172, 1964.
guinea pig	LD50	subcutaneous	170mg/kg (170mg/kg)	BEHAVIORAL: TREMOR GASTROINTESTINAL: NAUSEA OR VOMITING BEHAVIORAL: MUSCLE CONTRACTION OR SPASTICITY)	Medicina del Lavoro. Industrial Medicine. Vol. 47, Pg. 192, 1956.
guinea pig	LD50	unreported	173mg/kg (173mg/kg)	BEHAVIORAL: TREMOR BEHAVIORAL: CHANGES IN MOTOR ACTIVITY (SPECIFIC ASSAY) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD	Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 43(9), Pg. 38, 1978.
mammal (species unspecified)	LD50	oral	100mg/kg (100mg/kg)		Kagaku to Seibutsu. Chemistry and Biology. Vol. 17, Pg. 495, 1979.
mammal (species unspecified)	LDLo	intravenous	190mg/kg (190mg/kg)		Comptes Rendus Hebdomadaires des Seances, Academie des Sciences. Vol. 153, Pg. 895, 1911.
mouse	LD50	intraperitoneal	170mg/kg (170mg/kg)		Toxicology and Applied Pharmacology. Vol. 33, Pg. 142, 1975.
mouse	LD50	oral	107mg/kg (107mg/kg)		Archives of Toxicology. Vol. 47, Pg. 179, 1981.
mouse	LD50	unreported	156mg/kg (156mg/kg)	BEHAVIORAL: TREMOR BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD BEHAVIORAL: CHANGES IN MOTOR ACTIVITY (SPECIFIC ASSAY)	Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 43(9), Pg. 38, 1978.
quail	LD50	oral	186mg/kg (186mg/kg)	PERIPHERAL NERVE AND SENSATION: FLACCID PARALYSIS WITHOUT ANESTHESIA (USUALLY NEUROMUSCULAR BLOCKAGE) BEHAVIORAL: ALTERED SLEEP TIME (INCLUDING CHANGE IN RIGHTING REFLEX) BEHAVIORAL: CHANGES IN MOTOR ACTIVITY (SPECIFIC ASSAY)	Journal of Toxicology and Environmental Health. Vol. 7, Pg. 935, 1981.
rabbit	LD50	oral	150mg/kg (150mg/kg)		Toxicology and Applied Pharmacology. Vol. 6, Pg. 172, 1964.
rabbit	LD50	skin	1680uL/kg (1.68mL/kg)	BEHAVIORAL: "HALLUCINATIONS, DISTORTED PERCEPTIONS"	Acute Toxicity Data. Journal of the American College of Toxicology, Part B. Vol. 1, Pg. 115, 1990.
rabbit	LD50	unreported	280mg/kg (280mg/kg)	BEHAVIORAL: TREMOR BEHAVIORAL: CHANGES IN MOTOR ACTIVITY (SPECIFIC ASSAY) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD	Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 43(9), Pg. 38, 1978.
rat	LD50	intraperitoneal	90mg/kg (90mg/kg)		Archives des Maladies Professionnelles de Medecine du Travail et de Securite Sociale. Vol. 36, Pg. 58, 1975.
rat	LD50	oral	124mg/kg (124mg/kg)		Archives des Maladies Professionnelles de Medecine du Travail et de Securite Sociale. Vol. 36, Pg. 58, 1975.
rat	LD50	skin	400mg/kg (400mg/kg)	BLOOD: OTHER CHANGES	Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 44(10), Pg. 73, 1979.
rat	LD50	unreported	208mg/kg (208mg/kg)	BEHAVIORAL: TREMOR BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD BEHAVIORAL: CHANGES IN MOTOR ACTIVITY (SPECIFIC ASSAY)	Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 43(9), Pg. 38, 1978.

Acrylamide Consensus Reports

NTP 10th Report on Carcinogens. IARC Cancer Review: Group 2B MELAAD Medicina del Lavoro. Industrial Medicine. 47 (1956),192. ; Animal Sufficient Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 39 (1986),p. 41 . EPA Extremely Hazardous Substances List. Community Right-To-Know List. Reported in EPA TSCA Inventory.

Acrylamide Safety Profile

Safety Information of Acrylamide (CAS NO.79-06-1):
Hazard Codes: T Toxic
Risk Statements: 45-46-20/21-25-36/38-43-48/23/24/25-62-48/20/21/22-22-24/25
R45:May cause cancer.
R46:May cause heritable genetic damage.
R20/21:Harmful by inhalation and in contact with skin.
R25 :Toxic if swallowed.
R36/38:Irritating to eyes and skin.
R43:May cause sensitization by skin contact.
R48:Danger of serious damage to health by prolonged exposure.
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed.
R62:Risk of impaired fertility.
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed.
R22:Harmful if swallowed.
R45:May cause cancer.
Safety Statements: 53-45-24-36/37/39-26-36/37
S53:Avoid exposure - obtain special instructions before use.
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37:Wear suitable protective clothing and gloves.
RIDADR: UN 3426 6.1/PG 3
WGK Germany: 3
RTECS: AS3325000
F: 8-10
HazardClass: 6.1
PackingGroup: III
HS Code: 29241900

Acrylamide Standards and Recommendations

OSHA PEL: TWA 0.03 mg/m³ (skin)
ACGIH TLV: Animal Carcinogen, TWA 0.03 mg/m³ (skin)
DFG MAK: Animal Carcinogen, Suspected Human Carcinogen
NIOSH REL: TWA 0.3 mg/m³
DOT Classification: 6.1; Label: KEEP AWAY FROM FOOD

Acrylamide Analytical Methods

For occupational chemical analysis use OSHA: #21.

Acrylamide Specification

Acrylamide , its CAS NO. is 79-06-1, the synonyms are Optimum ; Propenamide ; Propeneamide ; Propenoic acid amide .

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