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Basic information

  • Name:

  • Allethrin

  • CAS No.:

  • 584-79-2

  • Formula:
  • C19H26O3
  • Synonyms:
  • Chrysanthemummonocarboxylicacid, 3-allyl-2-methyl-4-oxo-2-cyclopenten-1-yl ester (6CI);Cyclopropanecarboxylic acid, 2,2-dimethyl-3-(2-methyl-1-propenyl)-,2-methyl-4-oxo-3-(2-propenyl)-2-cyclopenten-1-yl ester (9CI);2-Cyclopenten-1-one,2-allyl-4-hydroxy-3-methyl-,2,2-dimethyl-3-(2-methylpropenyl)cyclopropanecarboxylate (8CI);2,2-Dimethyl-3-(2-methyl-1-propenyl)cyclopropanecarboxylic acid, ester with2-allyl-4-hydroxy-3-methyl-2-cyclopenten-1-one;2-Allyl-4-hydroxy-3-methyl-2-cyclopenten-1-one ester of 2,2-dimethyl-3-(2-methylpropenyl)cyclopropanecarboxylic acid;3-(2-Propenyl)-2-methyl-4-oxo-2-cyclopentenyl3,3-dimethyl-2-(2-methyl-1-propenyl)cyclopropanecarboxylate;Allethrine;Allyl cinerin I;Bioallethrin;Depallethrine;EBT;ENT 17510;Esbiothrine;Matox;NSC 11782;OMS 3045;Pynamin forte;Pyresyn;RU 27436;Wasp Stopper CF;dl,d-T80 allethrin;trans-Allethrin;

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Chemistry


IUPAC Name: (2-Methyl-4-oxo-3-prop-2-enylcyclopent-2-en-1-yl)2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate
Empirical Formula: C19H26O3
Molecular Weight: 302.4079
Index of Refraction: 1.515
Molar Refractivity: 86.75 cm3
Molar Volume: 287.5 cm3
Surface Tension: 36.3 dyne/cm
Density: 1.05 g/cm3
Flash Point: 166 °C
Enthalpy of Vaporization: 63.57 kJ/mol
Boiling Point: 386.8 °C at 760 mmHg
Vapour Pressure: 3.46E-06 mmHg at 25 °C
EINECS: 209-542-4
Classification Code of Allethrin (CAS NO.584-79-2): Agricultural Chemical; Insecticide; Insecticides; Mutation data; Pesticides

Uses

 Allethrin (CAS NO.584-79-2) is used in many household insecticides such as RAID as well as mosquito coils. Insects subject to its exposure become paralyzed before dying. They are also used as an ultra low volume spray for outdoor mosquito control.

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LC50 inhalation > 2gm/m3 (2000mg/m3)   Yakkyoku. Pharmacy. Vol. 37, Pg. 187, 1986.
mouse LD50 intraperitoneal 38mg/kg (38mg/kg)   Journal of Agricultural and Food Chemistry. Vol. 31, Pg. 250, 1983.
mouse LD50 oral 370mg/kg (370mg/kg)   Agricultural and Biological Chemistry. Vol. 28, Pg. 914, 1965.
mouse LD50 skin 1200mg/kg (1200mg/kg)   Agricultural and Biological Chemistry. Vol. 27, Pg. 684, 1963.
mouse LDLo intracrebral 4mg/kg (4mg/kg)   Toxicology and Applied Pharmacology. Vol. 66, Pg. 290, 1982.
quail LD50 oral 2030mg/kg (2030mg/kg)   Pesticide Manual. Vol. 9, Pg. 19, 1991.
rabbit LD50 intraperitoneal 11200mg/kg (11200mg/kg)   World Review of Pest Control. Vol. 3, Pg. 28, 1964.
rabbit LD50 oral 4290mg/kg (4290mg/kg)   Special Publication of the Entomological Society of America. Vol. 78-1, Pg. 7, 1978.
rabbit LD50 skin 11332mg/kg (11332mg/kg) BEHAVIORAL: TREMOR

BEHAVIORAL: EXCITEMENT		 AMA Archives of Industrial Hygiene and Occupational Medicine. Vol. 2, Pg. 420, 1950.
rat LCLo inhalation 13800mg/m3/4H (13800mg/m3) BEHAVIORAL: TREMOR

BEHAVIORAL: EXCITEMENT		 AMA Archives of Industrial Hygiene and Occupational Medicine. Vol. 2, Pg. 420, 1950.
rat LD50 oral 685mg/kg (685mg/kg)   Farm Chemicals Handbook. Vol. -, Pg. C255, 1991.
rat LD50 skin 2500mg/kg (2500mg/kg)   Yakkyoku. Pharmacy. Vol. 37, Pg. 187, 1986.
rat LD50 unreported 680mg/kg (680mg/kg)   "Chemistry of Pesticides," Melnikov, N.N., New York, Springer-Verlag New York, Inc., 1971Vol. -, Pg. 131, 1971.
rat LDLo intravenous 4mg/kg (4mg/kg) BEHAVIORAL: TREMOR

BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD

BEHAVIORAL: AGGRESSION		 Pesticide Biochemistry and Physiology. Vol. 2, Pg. 308, 1972.

Safety Profile

Hazard Codes:HarmfulXn,DangerousN
Risk Statements:  20/22-50/53 
R20/22:Harmful by inhalation and if swallowed. 
R50/53:Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Statements:  36-60-61 
S60:This material and its container must be disposed of as hazardous waste. 
S61:Avoid release to the environment. Refer to special instructions / safety data sheets. 
S36:Wear suitable protective clothing.
RIDADR:  UN 3352

Specification

 Allethrin (CAS NO.584-79-2), its Synonyms are  (+)-Allelrethonyl (+)-cis,trans-chrysanthemate ; (+)-trans-Chrysanthemumic acid ester of (+-)-allethrolone ; (RS)-3-Allyl-2-methyl-4-oxocyclopent-2-enyl (+-)-cis,trans-chrysanthemate ; 3-Allyl-2-methyl-4-oxo-2-cyclopenten-1-yl chrysanthemate ; Allethrolone ester of chrysanthemummonocarboxylic acid ; Cinerin I allyl homolog .

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