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Name	Aluminium bromide	EINECS	231-779-7
CAS No.	7727-15-3	Density	3.205 g/mL at 25 °C(lit.)
PSA	0.00000	LogP	2.53680
Solubility	decomposes in water	Melting Point	94-98 °C(lit.)
Formula	AlBr₃	Boiling Point	265 °C
Molecular Weight	266.694	Flash Point	268°C subl.
Transport Information	UN 3264 8/PG 2	Appearance	white crystalline powder
Safety	9-16-26-29-36/37/39-43-45-60-61-62-28-27	Risk Codes	23/24/25-34-22-14-67-65-50/53-11
Molecular Structure		Hazard Symbols	C,Xi,N,F
Synonyms	Aluminumbromide (8CI);Aluminum tribromide;Aluminum tribromide (AlBr3);NSC 87608;Aluminum bromide(AlBr3);	Article Data	70

Aluminium bromide Synthetic route

: 3530-39-0
phenylaluminium dichloride

: 106-95-6
allyl bromide

A: 300-57-2
allylbenzene

B: 92-52-4
biphenyl

C: 7727-15-3
aluminium bromide

Conditions

Conditions	Yield
bis(η3-allyl-μ-chloropalladium(II)) In diethyl ether Ar atmosphere; stirring (20°C, 5 mole-% catalyst, 8 h);	A 94% B <1 C n/a
tetrakis(triphenylphosphine) palladium(0) In diethyl ether Ar atmosphere; stirring (20°C, 5 mole-% catalyst, 20 h);	A <1 B <1 C n/a

: 6591-30-6
diphenylaluminum chloride

: 106-95-6
allyl bromide

A: 300-57-2
allylbenzene

B: 92-52-4
biphenyl

C: 7727-15-3
aluminium bromide

Conditions

Conditions	Yield
tetrakis(triphenylphosphine) palladium(0) In diethyl ether Ar atmosphere; stirring (20°C, 5 mole-% catalyst, 20 h);	A 37% B <1 C n/a

: 74-95-3
1,1-dibromomethane

aluminium: aluminium

A: 74-85-1
ethene

B: 7727-15-3
aluminium bromide

: 75-25-2
Bromoform

aluminium: aluminium

: 7727-15-3
aluminium bromide

Conditions

Conditions	Yield
Erhitzen des Reaktionsprodukts im Vakuum auf 200grad;

: 1333-84-2, 1344-28-1
aluminum oxide

: 7727-15-3
aluminium bromide

Conditions

Conditions	Yield
With bromine; pyrographite In not given heating;
With bromine; pyrographite heating;
With sulfur dibromide In solid 350°C, with vaporous sulfur bromide;

: 1333-84-2, 1344-28-1
aluminum oxide

: 13172-31-1
disulphur dibromide

: 7727-15-3
aluminium bromide

Conditions

Conditions	Yield
reaction started at 350°C and accelerated by raising of temp.; excess of S2Br2 removed with HBr or nitrogen;
reaction started at 350°C and accelerated by raising of temp.; excess of S2Br2 removed with HBr or nitrogen;

: 7726-95-6
bromine

: 7727-15-3
aluminium bromide

Conditions

Conditions	Yield
With aluminum(III) sulfate In water heating on water bath with small amt. of Br2 and H2O;
With bisilicates; carbon heating;
With carbon; silicates heating;

: 7784-27-2
aluminium trinitrate

: 7726-95-6
bromine

: 7727-15-3
aluminium bromide

Conditions

Conditions	Yield
In not given heating on water bath with small amt. of Br2;
In not given heating on water bath with small amt. of Br2;

: 7726-95-6
bromine

: 7429-90-5
aluminium

: 7727-15-3
aluminium bromide

Conditions

Conditions	Yield
In gas Al and Br2 in vac. were vaporized separately and reacted in gaseous state; distd. in vac.;
With air; water in moist air containing Br2 condensation of droplets of a soln. of AlBr3 occurs on a gray layer that has formed first;;
In neat (no solvent) start of react. by heating;;

: 7429-90-5
aluminium

: 7727-15-3
aluminium bromide

Conditions

Conditions	Yield
With bromine reacted in the presence of AlBr3;
With bromine Al heated in combustion tube; with H2 or N2 deluted Br2 lead over Al;
With bromine Al sheet heated in combustion tube; vaporous Br2 leaded over Al; AlBr3 flowed out from tube;

Aluminium bromide Chemical Properties

IUPAC Name: Tribromoalumane
Molecular Formula: AlBr₃
Formula Weight: 266.69g/mol
EINECS: 231-779-7
Melting Point: 94-98 °C(lit.)
Boiling Point: 265 °C
Density: 3.205 g/mL at 25 °C(lit.)
Vapor Pressure: 1 mm Hg ( 81.3 °C)
Flash Point: 268°C subl.
Chemical Properties: White crystalline powder
Water Solubility: Decomposes
Sensitive: Moisture sensitive
Stability: Stable, but reacts violently with water. Incompatible with aqueous solutions, alcohols, acids.
Synonyms of Aluminium bromide (7727-15-3): Aluminum bromide ; Aluminum bromide Hexahydrate ; Aluminium tribromide ; AlBr3 ; Aluminum bromide (AlBr3); Aluminum bromide , anhydrous ; Aluminumbromide (albr3)
Product Categories of Aluminium bromide (7727-15-3): Inorganics ; Aluminum salts ; Aluminummetal and ceramic science ; Aluminumsynthetic reagents ; Catalysis and inorganic chemistry ; Chemical synthesis ; Crystal grade inorganics ; Lewis acids ; Salts
Structure of Aluminium bromide (7727-15-3):

Aluminium bromide Safety Profile

Safety Statements: 9-16-26-29-36/37/39-43-45
9: Keep container in a well-ventilated place
16: Keep away from sources of ignition - No smoking
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
29: Do not empty into drains
36/37/39: Wear suitable protective clothing, gloves and eye/face protection
43: In case of fire, use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add - Never use water)
45: In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
WGK Germany: 3
Hazard Note: Irritant
Hazard Class: 8
Risk Statements: 23/24/25-34-22-14-67-65-50/53-11
23/24/25: Toxic by inhalation, in contact with skin and if swallowed
34: Causes burns
22: Harmful if swallowed
14: Reacts violently with water
67: Vapors may cause drowsiness and dizziness
65: Harmful: May cause lung damage if swallowed
50/53: Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
11: Highly Flammable

Aluminium bromide Specification

General Description: A white to yellowish-red lumpy solid with a pungent odor.

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